Compositions with improved urease-inhibiting effect comprising (thio)phosphoric acid triamide and further compounds

ABSTRACT

An composition comprising:
         (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I)       

       R 1 R 2 N—P(X)(NH 2 ) 2 ,
         wherein   X is oxygen or sulfur;   R 1  is a C 1  to C 20  alkyl, C 3  to C 20  cycloalkyl, C 6  to C 20  aryl, or dialkylaminocarbonyl group;   R 2  is H, or   R 1  and R 2  together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur,   and   (C) at least one amine selected from the group consisting of   (C1) a polymeric polyamine, and   (C2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C 2  to C 12  alkyl groups R 21 , wherein at least one of the groups R 21  is different to the other groups R 21 , and   (C3) an amine containing not more than one amino group and at least two alkoxy- or hydroxy-substituted C 2  to C 12  alkyl groups R 22 , wherein at least one of the groups R 22  bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R 22  is different to the other group(s) R 22 , and   (C4) an amine containing at least one saturated or unsaturated C 8  to C 40  alkyl group R 23 , and   (C5) a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group.

CROSS REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. application Ser. No. 14/902,181, filed Dec. 30, 2015, the entire contents of which is incorporated herein in its entirety. U.S. application Ser. No. 14/902,181, is a National Stage application of International Application No. PCT/IB2014/062667, filed Jun. 27, 2014, which claims the benefit of International Application No. PCT/IB2013/055484, filed Jul. 4, 2013; International Application No. PCT/IB2013/055486, filed Jul. 4, 2013; and International Application No. PCT/IB2013/055483, filed Jul. 4, 2013, the contents of which are incorporated herein by reference in their entirety.

DESCRIPTION Field of the Invention

This invention essentially relates to compositions with improved urease-inhibiting effect comprising (thio)phosphoric acid triamide and further compounds and the use of such compositions as additive or coating material for nitrogen-containing fertilizers.

Description of the Prior Art

Worldwide, the predominant and further-increasing amount of the nitrogen used for fertilizing is employed in the form of urea or urea-containing fertilizers. Urea itself, however, is a form of nitrogen which is absorbed very little if at all, being hydrolyzed relatively rapidly by the enzyme urease, which is present ubiquitously in the soil, to form ammonia and carbon dioxide. In this process, in certain circumstances, gaseous ammonia is emitted to the atmosphere, and is then no longer available in the soil for the plants, thereby lowering the efficiency of fertilization.

It is known that the degree of utilization of the nitrogen when using urea-containing fertilizers can be improved by spreading urea-containing fertilizers together with substances which are able to inhibit or decrease the enzymatic cleavage of urea (for a general review, see Kiss, S. Simihäian, M. (2002) Improving Efficiency of Urea Fertilizers by Inhibition of Soil Urease Activity, ISBN 1-4020-0493-1, Kluwer Academic Publishers, Dordrecht, The Netherlands). Among the most potent known urease inhibitors are N-alkylthiophosphoric acid triamides and N-alkylphosphoric acid triamides, which are described in EP 0 119 487, for example.

Additionally, mixtures of N-alkylthiophosphoric acid triamides such as N-(n-butyl)thiophosphoric acid triamide (NBPT) and N-(n-propyl)thiophosphoric acid triamide (NPPT) can be used. The mixtures and their preparation are described in US 2010/218575 A1, for example.

These urease inhibitors are described in U.S. Pat. No. 4,530,714, for example. In order for this class of compound to be able to act as a urease inhibitor, there must first be a conversion to the corresponding oxo form. That form reacts subsequently with the urease, causing its inhibition.

It is advisable to apply the urease inhibitors together with the urea onto or into the soil, since this ensures that the inhibitor comes into contact, together with the fertilizer, with the soil. The urease inhibitor may be incorporated in the urea by, for example, dissolving it into the melt prior to urea granulation or prilling. A process of this kind is described in U.S. Pat. No. 5,352,265, for example. A further option is to apply the urease inhibitor to the urea granules or prills, in the form of a solution, for example.

Corresponding processes for application, and suitable solvents, are described in US 2010/218575 A1, for example. Other suitable additives, for example amines selected from methyldiethanolamine, tetrahydroxypropylethylenediamine, trimethylaminoethylethanolamine, N,N,N′,N′-tetramethyl-1,6-hexanediamine, N,N′,N″-tris(dimethylaminopropyl)hexahydrotriazine, and 2,2′-dimorpholinyldiethyl ether, are described in US 2011/0154874 A1.

The storage life of the urease inhibitor is limited. The higher the temperature, the shorter the storage life. If, for example, urea is stored under tropical conditions, a major part of the urease inhibitor has undergone decomposition, generally, after about four weeks of storage. If the urease inhibitor is introduced into the urea melt, the decomposition is less. For the commercialization of the urea stabilized with the urease inhibitor, however, it is often vital to apply the urease inhibitor to urea and to store the treated fertilizer until the time of its spreading to the soil.

OBJECTS OF THE INVENTION

One of the objects of the present invention was to provide a composition containing (thio)phosphoric acid triamide which

-   -   (i) enhances the stability of the (thio)phosphoric acid         triamide(s), and/or     -   (ii) has a relatively long storage life, particularly before         being applied to or coated on nitrogen-containing fertilizers,         and/or     -   (iii) enhances the stability of the (thio)phosphoric acid         triamide particularly when applied to or coated on         nitrogen-containing fertilizers such as urea, and/or     -   (iv) protects the (thio)phosphoric acid triamide applied to or         coated on nitrogen-containing fertilizers such as urea from         decomposition or loss, and/or     -   (v) is toxicologically unobjectionable, and/or     -   (vi) does not adversely affect the urease-inhibiting effect         and/or activity of the (thio)phosphoric acid triamide, and/or     -   (vii) can be easily and safely packaged, transported and         shipped, even in large quantities,     -   (viii) can be easily and safely handled and applied for soil         treatment, even in large quantities.

SUMMARY OF THE INVENTION

Accordingly, a composition (Q1) was found which comprises:

(A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I)

R¹R²N—P(X)(NH₂)₂,

-   -   wherein     -   X is oxygen or sulfur;     -   R¹ is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl,         or dialkylaminocarbonyl group;     -   R² is H, or     -   R¹ and R² together with the nitrogen atom linking them define a         5- or 6-membered saturated or unsaturated heterocyclic radical,         which optionally comprises 1 or 2 further heteroatoms selected         from the group consisting of nitrogen, oxygen, and sulfur,     -   and

(B) an aromatic alcohol according to the general formula (II).

R¹¹—C(R¹²)(R¹³)—OH,

-   -   in an amount of more than 10 wt. % (wt. % stands for “percent by         weight”) based on the total weight of the composition (Q1),     -   wherein     -   R¹¹ is aryl or alkylaryl;     -   R¹² is H or alkyl;     -   R¹³ is H or alkyl.

Accordingly, a further composition (Q2) was found which comprises:

(A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I)

R¹R²N—P(X)(NH₂)₂,

-   -   wherein     -   X is oxygen or sulfur;     -   R¹ is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl,         or dialkylaminocarbonyl group;     -   R² is H, or     -   R¹ and R² together with the nitrogen atom linking them define a         5- or 6-membered saturated or unsaturated heterocyclic radical,         which optionally comprises 1 or 2 further heteroatoms selected         from the group consisting of nitrogen, oxygen, and sulfur,     -   and

(C) at least one amine selected from the group consisting of

-   -   (C1) a polymeric polyamine, and     -   (C2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups R²¹, wherein at least one of the groups R²¹ is different         to the other groups R²¹, and     -   (C3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups         R²², wherein at least one of the groups R²² bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein at least one of the groups R²² is different to the other         group(s) R²², and     -   (C4) an amine containing at least one saturated or unsaturated         C₈ to C₄₀ alkyl group R²³, and     -   (C5) a saturated or unsaturated heterocyclic amine which         contains at least one oxygen atom as ring atom and which does         not contain a further alkoxy group.

Accordingly, yet a further composition (Q3) was found which comprises:

(A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I)

R¹R²N—P(X)(NH₂)₂,

-   -   wherein     -   X is oxygen or sulfur;     -   R¹ is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl,         or dialkylaminocarbonyl group;     -   R² is H, or     -   R¹ and R² together with the nitrogen atom linking them define a         5- or 6-membered saturated or unsaturated heterocyclic radical,         which optionally comprises 1 or 2 further heteroatoms selected         from the group consisting of nitrogen, oxygen, and sulfur,     -   and

(D) at least one amide according to the general formula (III)

R³¹CO—NR³²R³³

-   -   wherein     -   R³¹CO is an acyl radical having 1 to 22 carbon atoms,     -   R³² is hydrogen or alkyl, and     -   R³³ is hydrogen or alkyl, or     -   R³² and R³³ together with the nitrogen atom linking them define         a 5- or 6-membered saturated or unsaturated heterocyclic         radical, which optionally comprises 1 or 2 further heteroatoms         selected from the group consisting of nitrogen, oxygen, and         sulfur.

In addition, a process for treating the soil comprising applying the compositions of the invention into the soil in-furrow and/or as side dress and/or as broadcast was found.

Moreover, the use of the compositions of the invention as additive or coating material for nitrogen-containing fertilizers has been found.

Preferred embodiments are explained in the claims and the specification. It is understood that combinations of preferred embodiments are within the scope of the present invention.

The term “at least one” is to be understood as 1, 2, 3 or more. A mixture comprising at least one amine refers for example to a mixture comprising 1, 2, 3 or more amines.

The term “soil” is to be understood as a natural body comprised of living (e.g. microorganisms (such as bacteria and fungi), animals and plants) and non-living matter (e.g. minerals and organic matter (e.g. organic compounds in varying degrees of decomposition), liquid, and gases) that occurs on the land surface, and is characterized by soil horizons that are distinguishable from the initial material as a result of various physical, chemical, biological, and anthropogenic processes. From an agricultural point of view, soils are predominantly regarded as the anchor and primary nutrient base for plants (plant habitat).

The term “fertilizer” is to be understood as chemical compounds applied to promote plant and fruit growth. Fertilizers are typically applied either through the soil (for uptake by plant roots) or by foliar feeding (for uptake through leaves). The term “fertilizer” can be subdivided into two major categories: a) organic fertilizers (composed of decayed plant/animal matter) and b) inorganic fertilizers (composed of chemicals and minerals). Organic fertilizers include manure, slurry, worm castings, peat, seaweed, sewage, and guano. Green manure crops are also regularly grown to add nutrients (especially nitrogen) to the soil. Manufactured organic fertilizers include compost, blood meal, bone meal and seaweed extracts. Further examples are enzymatically digested proteins, fish meal, and feather meal. The decomposing crop residue from prior years is another source of fertility. In addition, naturally occurring minerals such as mine rock phosphate, sulfate of potash and limestone are also considered inorganic fertilizers. Inorganic fertilizers are usually manufactured through chemical processes (such as the Haber-Bosch process), also using naturally occurring deposits, while chemically altering them (e.g. concentrated triple superphosphate). Naturally occurring inorganic fertilizers include Chilean sodium nitrate, mine rock phosphate, and limestone.

“Manure” is organic matter used as organic fertilizer in agriculture. Depending on its structure, manure can be divided into liquid manure, semi-liquid manure, stable or solid manure and straw manure. Depending on its origin, manure can be divided into manure derived from animals or plants. Common forms of animal manure include feces, urine, farm slurry (liquid manure) or farmyard manure (FYM) whereas FYM also contains a certain amount of plant material (typically straw), which may have been used as bedding for animals. Animals from which manure can be used comprise horses, cattle, pigs, sheep, chickens, turkeys, rabbits, and guano from seabirds and bats. The application rates of animal manure when used as fertilizer highly depends on the origin (type of animals). Plant manures may derive from any kind of plant whereas the plant may also be grown explicitly for the purpose of plowing them in (e.g. leguminous plants), thus improving the structure and fertility of the soil. Furthermore, plant matter used as manure may include the contents of the rumens of slaughtered ruminants, spent hops (left over from brewing beer) or seaweed.

The compositions of the invention are referred to as the compositions (Q1), (Q2), and (Q3) in the following. The composition (Q1) comprises (A) and (B)—latter in an amount of more than 10wt. % based on the total weight of (Q1)—and optionally further components as described below. The composition (Q2) comprises (A) and (C) and optionally further components as described below. The composition (Q3) comprises (A) and (D) and optionally further components as described below.

According to the invention, the compositions (Q1), (Q2), and (Q3) comprises—as one of their essential components—

(A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I)

R¹R²N—P(X)(NH₂)₂,

-   -   wherein     -   X is oxygen or sulfur;     -   R¹ is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl,         or dialkylaminocarbonyl group;     -   R² is H, or     -   R¹ and R² together with the nitrogen atom linking them define a         5- or 6-membered saturated or unsaturated heterocyclic radical,         which optionally comprises 1 or 2 further heteroatoms selected         from the group consisting of nitrogen, oxygen, and sulfur.

X in the general formula (I) of (A) is preferably sulfur.

R¹ in the general formula (I) of (A) is preferably C₁-C₂₀-alkyl, more preferably C₁-C₁₀-alkyl, most preferably C₂-C₇ alkyl, for example C₃-C₄ alkyl.

Examples of alkyl groups are methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sec-butyl, tert-butyl, pentyl, isopentyl, neopentyl, tert-pentyl, hexyl, 2-methylpentyl, heptyl, octyl, 2-ethylhexyl, isooctyl, nonyl, isononyl, decyl and isodecyl. Examples of cycloalkyl groups are cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl and cyclooctyl, examples of aryl groups are phenyl or naphthyl. Examples of heterocyclic radicals R₁R₂N— are piperazinyl, morpholinyl, pyrrolyl, pyrazolyl, triazolyl, oxazolyl, thiazolyl or imidazolyl groups.

According to one embodiment, (A) comprises N-n-butylthiophosphoric acid triamide (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT), preferably NBPT and NPPT.

According to another embodiment, (A) comprises at least two different (thio)phosphoric acid triamides having structures of the general formula (I) and wherein said at least two different (thio)phosphoric acid triamides differ in at least one of radicals R¹ or R², and preferably, one of said at least two different (thio)phosphoric acid triamides is N-n-butylthiophosphoric acid tramide (NBPT), and more preferably, the other of said at least two different (thio)phosphoric acid triamides is selected from the group consisting of N-cyclohexyl-, N-pentyl-, N-isobutyl- and N-n-propylphosphoric acid triamide and -thiophosphoric acid triamide. Especially preferred are mixtures (A) which comprise NBPT in amounts of from 40 to 95 wt. %, most preferably from 60 to 85% wt. %, particularly preferably from 72 to 80 wt. %, in each case based on the total weight of (A).

Generally, the mixture (A) can be contained in varying amounts in the composition (Q1), (Q2), or (Q3). Preferably, the amount of (A) is not more than 85 wt. % (wt. % stands for “percent by weight”), more preferably not more than 60 wt. %, most preferably not more than 45 wt. %, most particularly preferably not more than 35 wt. %, particularly not more than 30 wt. %, for example not more than 27 wt. %, based on the total weight of the composition (Q1), (Q2), or (Q3). Preferably, the amount of (A) is at least 1 wt. %, more preferably at least 4 wt. %, most preferably at least 10 wt. %, most particularly preferably at least 15 wt. %, particularly at least 20 wt. %, for example at least 23 wt. %, based on the total weight of the composition (Q1), (Q2), or (Q3).

According to the invention, the composition (Q1) comprises—as one of its essential components—

(B) an aromatic alcohol according to the general formula (II)

R¹¹—C(R¹²)(R¹³)—OH,

-   -   in an amount of more than 10 wt. % based on the total weight of         the composition (Q1),     -   wherein     -   R¹¹ is aryl or alkylaryl;     -   R¹² is H or alkyl;     -   R¹³ is H or alkyl.

The compositions (Q2) and (Q3) can further optionally comprise

(B) an aromatic alcohol according to the general formula (II)

R¹¹—C(R¹²)(R¹³)—OH,

-   -   wherein     -   R¹¹ is aryl or alkylaryl;     -   R¹² is H or alkyl;     -   R¹³ is H or alkyl.

The aromatic alcohol (B) is preferably used as solvent in the composition (Q1). If present, the aromatic alcohol (B) is preferably used as solvent in the compositions (Q2), or (Q3).

According to one embodiment, R¹² in the general formula (II) of (B) is C₁-C₄₀ alkyl, preferably C₁ to C₂₀ alkyl, more preferably C₁ to C₁₀ alkyl, most preferably C₁ to C₅ alkyl. According to another embodiment, R¹³ in the general formula (II) of (B) is C₁-C₄₀ alkyl, preferably C₁ to C₂₀ alkyl, more preferably C₁ to C₁₀ alkyl, most preferably C₁ to C₅ alkyl.

According to another embodiment, R¹² in the general formula (II) of (B) is H. According to another embodiment, R¹³ in the general formula (II) of (B) is H. According to another embodiment, R¹³ in the general formula (II) of (B) is H.

According to one embodiment, R¹¹ in the general formula (II) of (B) is aryl. According to another embodiment, R¹¹ in the general formula (II) of (B) is phenyl, naphthyl, pyridyl, or pyrrolyl, pyrazolyl, triazolyl, oxazolyl, thiazolyl or imidazolyl. According to another embodiment, R¹¹ in the general formula (II) of (B) is phenyl.

According to one embodiment, (B) is benzyl alcohol.

Generally, the aromatic alcohol (B) can be contained in any amounts greater than 10 wt. % in the composition (Q1) based on the total weight of the composition (Q1). Preferably, the amount of (B) is not more than 99 wt. % (wt. % stands for “percent by weight”), more preferably not more than 93 wt. %, most preferably not more than 87 wt. %, most particularly preferably not more than 80 wt. %, particularly not more than 75 wt. %, for example not more than 70 wt. %, based on the total weight of the composition (Q1). Preferably, the amount of (B) is at least 13 wt. %, more preferably at least 20 wt. %, most preferably at least 35 wt. %, most particularly preferably at least 45 wt. %, particularly at least 55 wt. %, for example at least 60 wt. %, based on the total weight of the composition (Q1).

According to another embodiment, the amount of (B) is preferably not more than 78 wt. %, more preferably not more than 67 wt. %, most preferably not more than 61 wt. %, most particularly preferably not more than 56 wt. %, particularly not more than 53 wt. %, for example not more than 50 wt. %, based on the total weight of the composition (Q1). Preferably, the amount of (B) is at least 16 wt. %, more preferably at least 21 wt. %, most preferably at least 26 wt. %, most particularly preferably at least 30 wt. %, particularly at least 37 wt. %, for example at least 40 wt. %, based on the total weight of the composition (Q1).

If present, the aromatic alcohol (B) can generally be contained in varying amounts in the composition (Q2) or (Q3). If present, the amount of (B) is preferably not more than 95 wt. % (wt. % stands for “percent by weight”), more preferably not more than 80 wt. %, most preferably not more than 70 wt. %, most particularly preferably not more than 60 wt. %, particularly not more than 55 wt. %, for example not more than 50 wt. %, based on the total weight of the composition (Q2) or (Q3). If present, the amount of (B) is preferably at least 6 wt. %, more preferably at least 13 wt. %, most preferably at least 21 wt. %, most particularly preferably at least 30 wt. %, particularly at least 35 wt. %, for example at least 40 wt. %, based on the total weight of the composition (Q2), or (Q3).

According to the invention, the composition (Q2) comprises—as one of its essential components—and the compositions (Q1) and (Q3) can further comprise—as one of its optional components—

(C) at least one amine selected from the group consisting of

-   -   (C1) a polymeric polyamine, and     -   (C2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups R²¹, wherein at least one of the groups R²¹ is different         to the other groups R²¹, and     -   (C3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups         R²², wherein at least one of the groups R²² bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein at least one of the groups R²² is different to the other         group(s) R²², and     -   (C4) an amine containing at least one saturated or unsaturated         C₈ to C₄₀ alkyl group R²³, and     -   (C5) a saturated or unsaturated heterocyclic amine which         contains at least one oxygen atom as ring atom and which does         not contain a further alkoxy group.

Generally, the amine(s) (C) can be contained in varying amounts in the composition (Q2). Preferably, the amount of (C) is not more than 90 wt. % (wt. % stands for “percent by weight”), more preferably not more than 65 wt. %, most preferably not more than 48 wt. %, most particularly preferably not more than 37 wt. %, particularly not more than 30 wt. %, for example not more than 24 wt. %, based on the total weight of the composition (Q2). Preferably, the amount of (C) is at least 1 wt. %, more preferably at least 3 wt. %, most preferably at least 6 wt. %, most particularly preferably at least 9 wt. %, particularly at least 14 wt. %, for example at least 18 wt. %, based on the total weight of the composition (Q2).

If present, the amine(s) (C) can generally be contained in varying amounts in the composition (Q1) or (Q3). If present, the amount of (C) is preferably not more than 90 wt. % (wt. % stands for “percent by weight”), more preferably not more than 65 wt. %, most preferably not more than 48 wt. %, most particularly preferably not more than 37 wt. %, particularly not more than 30 wt. %, for example not more than 24 wt. %, based on the total weight of the composition (Q1) or (Q3). If present, the amount of (C) is preferably at least 1 wt. %, more preferably at least 3 wt. %, most preferably at least 6 wt. %, most particularly preferably at least 9 wt. %, particularly at least 14 wt. %, for example at least 18 wt. %, based on the total weight of the composition (Q1) or (Q3).

According to one embodiment, (C) is

-   -   (C1) a polymeric polyamine.

Generally, (C1) can be any polymeric polyamine, and is preferably a polyalkyleneimine or polyvinylamine, more preferably a polyalkyleneimine, most preferably a polyethyleneimine, polypropyleneimine, or polybutyleneimine, particularly a polyethyleneimine.

According to one embodiment, (C1) is preferably any polymeric polyamine comprising ethyleneimine (—CH2CH2NH—) as monomeric units, including homopolymers and any copolymers of ethyleneimine, and is preferably a homopolymer of ethyleneimine. Copolymers can be alternating, periodic, statistical or block copolymers.

Generally, (C1) can be of any polymer structure, for example a linear polymer, a ring polymer, a cross-linked polymer, a branched polymer, a star polymer, a comb polymer, a brush polymer, a dendronized polymer, or a dendrimer etc. According to one embodiment, (C1) is an essentially linear polymer, and is preferably a linear polymer.

Polyethyleneimines which may be used are polyethyleneimine homopolymers which may be present in uncrosslinked or crosslinked form. The polyethyleneimine homopolymers can be prepared by known processes, as described, for example, in Römpps (Chemie Lexikon, 8th edition, 1992, pages 3532-3533), or in Ullmanns Enzyklopädie der Technischen Chemie, 4th edition, 1974, vol. 8, pages 212-213. and the literature stated there. They have a molecular weight in the range from about 200 to 1000000 g/mol. Corresponding commercial products are for example available under the name Lupasol® from BASF SE.

According to one embodiment of the invention, the polyethyleneimine (C1) is preferably a polyethylenimine having a degree of branching in the range of from 0.1 to 0.95 (also referred to as “highly branched polyethyleneimine”), and more preferably a polyethylenimine having a degree of branching in the range of from 0.25 to 0.90, more preferably a polyethylenimine having a degree of branching in the range of from 0.30 to 0.80, and most preferably a polyethylenimine having a degree of branching in the range of 0.50 to 0.80.

Highly branched polyethyleneimines are characterized by its high degree of branching, which can be determined for example via ¹³C-NMR spectroscopy, preferably in D₂O, and is defined as follows:

Degree of branching=D+T/D+T+L

D (dendritic) equals the percentage of tertiary amino groups, L (linear) equals the percentage of secondary amino groups, and T (terminal) equals the percentage of primary amino groups.

Generally, the polymeric polyamine (C1) can have different weight average molecular weights. The weight average molecular weight of (C1) is preferably at least 200, more preferably at least 400, most preferably at least 550, particularly at least 650, for example at least 750. The weight average molecular weight of (C1) is preferably not more than 10,000, more preferably not more than 4,000, most preferably not more than 1,900, particularly not more than 1,500, for example not more than 1,350. The weight average molecular weight can be determined by standard gel permeation chromatography (GPC) known to the person skilled in the art.

According to another embodiment, (C) is

-   -   (C2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups R²¹, wherein at least one of the groups R²¹ is different         to the other groups R²¹.

A number of groups R²¹ within (C2) is at least 3, preferably 3 to 5, more preferably 3 to 4, and most preferably 3.

The number of carbon atoms in each group R²¹ within (C2) is 2 to 12, preferably 2 to 9, more preferably 2 to 7, most preferably 2 to 5, particularly preferably 2 to 4, particularly 2 to 3, for example 3, wherein said number of carbon atoms does not include carbon atoms in any alkoxy groups or any other substituents of R²¹.

The groups R²¹ within (C2) are alkoxy- or hydroxy-substituted, preferably hydroxy-substituted. For one amine (C2), among the at least three groups R²¹, at least one of the groups R²¹ is different to the other groups R²¹, preferably one of the groups R²¹ is different to the other groups R²¹.

Preferably at least one of the groups R²¹, more preferably at least two of the groups R²¹, most preferably at least three of the groups R²¹, particularly all groups R²¹ is or are covalently bound to the amino group of the amine (C2).

According to another preferred embodiment, (C2)

-   -   is an amine containing not more than one amino group and at         least three hydroxy-substituted C₂ to C₈—or preferably C₂ to         C₅—alkyl groups R²¹, wherein at least one of the groups R²¹ is         different to the other groups R²¹,     -   is preferably an amine containing not more than one amino group         and at least three hydroxy-substituted C₂ to C₃ alkyl groups         R²¹, wherein at least one of the groups R²¹ is different to the         other groups R²¹,     -   is more preferably an amine containing not more than one amino         group and three hydroxy-substituted C₂ to C₃ alkyl groups R²¹         which are covalently bound to the amino group, wherein one of         the groups R²¹ is different to the other groups R²¹, and     -   is for example an amine selected from the group consisting of         Bis(hydroxyethyl)-isopropanolamine (DEIPA), and         1,1′-((2-Hydroxyethyl)imino)dipropan-2-ol.

According to another preferred embodiment, (C2) is an amine N(R²¹)₃ wherein R²¹ is a an alkoxy- or hydroxy-substituted—preferably a hydroxyl-substituted—C₂ to C₁₂—preferably a C₂ to C₇, more preferably a C₂ to C₃—alkyl group and wherein one of the groups R²¹ is different to the other group R²¹.

According to another preferred embodiment, (C2) is an amine N(R²¹)₃ wherein R²¹ is a an alkoxy- or hydroxy-substituted—preferably a hydroxyl-substituted—C₂ to C₁₂—preferably a C₂ to C₇, more preferably a C₂ to C₃—alkyl group and wherein one of the groups R²¹ is different to the other group R²¹ and wherein at least one of the groups R²¹ bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom.

According to another embodiment, (C) is

-   -   (C3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups         R²², wherein at least one of the groups R²² bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein at least one of the groups R²² is different to the other         group(s) R²².

A number of groups R²² within (C3) is at least 2, preferably 2 to 5, more preferably 2 to 4, and most preferably 2 to 3, for example 2.

The number of carbon atoms in each group R²² within (C3) is 2 to 12, preferably 2 to 9, more preferably 2 to 7, most preferably 2 to 5, particularly preferably 2 to 4, particularly 2 to 3, for example 3, wherein said number of carbon atoms does not include carbon atoms in any alkoxy groups or any other substituents of R²².

The groups R²² within (C3) are alkoxy- or hydroxy-substituted, preferably hydroxy-substituted. For one amine (C3), among the at least two groups R²², at least one of the groups R²² is different to the other group(s) R²², preferably one of the groups R²² is different to the other group(s) R₂₂.

Preferably at least one of the groups R²², more preferably at least two of the groups R²², most preferably all groups R²² is or are covalently bound to the amino group of the amine (C3).

Preferably at least one of the groups R²², more preferably one of the groups R²² bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom, particularly at a secondary carbon atom.

According to another preferred embodiment, (C3)

-   -   is an amine containing not more than one amino group and at         least two hydroxy-substituted C₂ to C₇ alkyl groups R²², wherein         at least one of the groups R²² bears the hydroxy substituent at         a secondary or tertiary carbon atom and wherein at least one of         the groups R²² is different to the other group(s) R²²,     -   is more preferably an amine containing not more than one amino         group and at least two hydroxy-substituted C₂ to C₄ alkyl groups         R²², wherein at least one of the groups R²² bears the hydroxy         substituent at a secondary carbon atom and wherein at least one         of the groups R²² is different to the other group(s) R²²,     -   is most preferably an amine containing not more than one amino         group and two hydroxy-substituted C₂ to C₃ alkyl groups R²²         which are covalently bound to the amino group of the amine (C3),         wherein at least one of the groups R²² bears the hydroxy         substituent at a secondary carbon atom and wherein one of the         groups R²² is different to the other group R^(22,)     -   is for example an amine selected from the group consisting of         1-((2-hydroxyethyl)amino)-propan-2-ol, and         N-Methyl-N-hydroxyethyl-isopropanolamine.

According to another preferred embodiment, (C3) is an amine R²⁴N(R²²)₂ wherein R²⁴ is H or a C₁ to C₁₂—preferably a C₁ to C₇, more preferably a C₁ to C₃—alkyl group and R²² is an alkoxy- or hydroxy-substituted—preferably a hydroxyl-substituted—C₂ to C₁₂ —preferably a C₂ to C₇, more preferably a C₂ to C₃—alkyl group and wherein at least one of the groups R²² bears the hydroxy substituent at a secondary carbon atom and wherein one of the groups R²² is different to the other group R²².

According to another embodiment, (C) is

-   -   (C4) an amine containing at least one saturated or unsaturated         C₈ to C₄₀ alkyl group R²³.

The number of carbon atoms in each group R²³ within (C4) is 8 to 40, preferably 8 to 32, more preferably 8 to 24, most preferably 8 to 19, particularly preferably 8 to 16.

The group R²³ within (C4) is saturated or unsaturated, preferably unsaturated.

According to another preferred embodiment, (C4) contains at least one alkoxy or hydroxy group, more preferably at least one alkoxy and at least one hydroxy groups, most preferably at least two alkoxy and at least one hydroxyl group, particularly at least four alkoxy and at least one hydroxyl group.

For example, (C4) is an amine selected from the group consisting of: ethoxylated (2) cocoalkylamine, ethoxylated (5) cocoalkylamine, ethoxylated (15) cocoalkylamine, ethoxylated (2) oleylamine, lauryl-dimethylamine, oleyl-dimethylamine, and 2-propylheptylamine ethoxylate (5 EO), 2-propylheptylamine ethoxylate (10 EO), and 2-propylheptylamine ethoxylate (20 EO).

According to another embodiment, (C) is

-   -   (C5) a saturated or unsaturated heterocyclic amine which         contains at least one oxygen atom as ring atom and which does         not contain a further alkoxy group.

The term “heterocyclic amine” stands for a heterocyclic compound in which at least one ring atom of the heterocyclic ring is a nitrogen atom.

The heterocyclic amine (C5) is saturated or unsaturated, preferably saturated.

The heterocyclic amine (C5) contains preferably a 5-, 6- or 7-membered heterocyclic ring, more preferably a 5- or 6-membered ring, most preferably a 6-membered ring.

The heterocyclic amine (C5) contains at least one, more preferably 1 to 3, most preferably 1 to 2, particularly one oxygen atom(s) as ring atom(s) of the heterocyclic ring.

The heterocyclic amine (C5) is preferably a morpholine or morpholine derivative, more preferably N-alkyl morpholine, most preferably N-methyl, N-ethyl, N-propyl, or N-butyl morpholine, for example N-methyl morpholine.

According to the invention, the composition (Q3) comprises—as one of its essential components—and the compositions (Q1) and (Q2) can further comprise—as one of its optional components—

(D) at least one amide according to the general formula (III)

R³¹CO—NR³²R³³

-   -   wherein     -   R³¹CO is an acyl radical having 1 to 22 carbon atoms;     -   R³² is H or alkyl, and     -   R³³ is H or alkyl, or     -   R³² and R³³ together with the nitrogen atom linking them define         a 5- or 6-membered saturated or unsaturated heterocyclic         radical, which optionally comprises 1 or 2 further heteroatoms         selected from the group consisting of nitrogen, oxygen, and         sulfur.

Generally, the amide(s) (D) can be contained in varying amounts in the composition (Q3). Preferably, the amount of (D) is not more than 90 wt. % (wt. % stands for “percent by weight”), more preferably not more than 65 wt. %, most preferably not more than 45 wt. %, most particularly preferably not more than 30 wt. %, particularly not more than 22 wt. %, for example not more than 16 wt. %, based on the total weight of the composition (Q3). Preferably, the amount of (D) is at least 1 wt. %, more preferably at least 3 wt. %, most preferably at least 6 wt. %, most particularly preferably at least 9 wt. %, particularly at least 12 wt. %, for example at least 15 wt. %, based on the total weight of the composition (Q3).

If present, the amide (D) can generally be contained in varying amounts in the composition (Q1) or (Q2). If present, the amount of (D) is preferably not more than 90 wt. % (wt. % stands for “percent by weight”), more preferably not more than 65 wt. %, most preferably not more than 45 wt. %, most particularly preferably not more than 30 wt. %, particularly not more than 22 wt. %, for example not more than 16 wt. %, based on the total weight of the composition (Q1) or (Q2). If present, the amount of (D) is preferably at least 1 wt. %, more preferably at least 3 wt. %, most preferably at least 6 wt. %, most particularly preferably at least 9 wt. %, particularly at least 12 wt. %, for example at least 15 wt. %, based on the total weight of the composition (Q1) or (Q2).

In the general formula (III) of (D) R³² is H or alkyl, preferably H or C₁ to C₄₀ alkyl, more preferably H or C₁ to C₂₀ alkyl, most preferably H or C₁ to C₁₀ alkyl, particularly preferably H or C₁ to C₄ alkyl, most particularly preferably C₁ to C₄ alkyl, particularly C₁ to C₂ alkyl, for example methyl.

In the general formula (III) of (D) R³³ is H or alkyl, preferably H or C₁ to C₄₀ alkyl, more preferably H or C₁ to C₂₀ alkyl, most preferably H or C₁ to C₁₀ alkyl, particularly preferably H or C₁ to C₄ alkyl, most particularly preferably C₁ to C₄ alkyl, particularly C₁ to C₂ alkyl, for example methyl.

According to one preferred embodiment, in the general formula (III) of (D) R³² is H or C₁ to C₄ alkyl, and R³³ is H or C₁ to C₄ alkyl, more preferably, R³² is C₁ to C₄ alkyl, and R³³ is C₁ to C₄ alkyl, most preferably, R³² is C₁ to C₂ alkyl, and R³³ is C₁ to C₂ alkyl.

According to one preferred embodiment (D1PE), in the general formula (III) of (D) R³¹CO is a hydroxysubstituted acyl radical having 1 to 22 carbon atoms, and more preferably, R³¹CO is a hydroxysubstituted acyl radical having 1 to 22 carbon atoms, and R³² is alkyl, and R³³ is alkyl, and most preferably, R³¹CO is a hydroxysubstituted acyl radical having 1 to 7 carbon atoms, and R³² is C₁ to C₄ alkyl, and R³³ is C₁ to C₄ alkyl.

According to another preferred embodiment, the amide (D) is a N,N-dialkyl amide based on lactic acid, citric acid, tartaric acid, ricinoleic acid, 12-hydroxy stearic acid, or their mixtures, preferably a N,N-dialkyl amide based on lactic acid, citric acid, tartaric acid, or their mixtures, most preferably a N,N-dimethyl amide based on lactic acid, citric acid, tartaric acid, particularly a lactic acid N,N-dimethylamide.

According to another preferred embodiment (D2PE), in the general formula (III) of (D) R³¹CO is an acyl radical having 6 to 12 carbon atoms, more preferably, R³¹CO is an acyl radical having 8 to 10 carbon atoms.

According to another preferred embodiment, in the general formula (III) of (D) R³¹CO does not contain a hydroxy group, and more preferably, R³¹CO does not contain a hydroxy group and is an acyl radical having 6 to 12 carbon atoms, and most preferably, R³¹CO does not contain a hydroxy group and is an acyl radical having 8 to 10 carbon atoms. For example, the amide (D) is selected from the group consisting of N,N-dimethyloctanamide, N,N-dimethylnonanamide, and N,N-dimethyldecanamide.

According to another preferred embodiment (D3PE), in the general formula (III) of (D) R³¹CO is an acyl radical having 1 to 3 carbon atoms, more preferably, R³¹CO is an acyl radical having 1 to 2 carbon atoms.

According to another preferred embodiment, in the general formula (Ill) of (D) R³² and R³³ together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and more preferably, R³² and R³³ together with the nitrogen atom linking them define a 6-membered saturated or unsaturated heterocyclic radical which optionally comprises one further heteroatom selected from the group consisting of nitrogen, oxygen, and sulfur, most preferably R³² and R³³ together with the nitrogen atom linking them define a 6-membered saturated heterocyclic radical which comprises one further oxygen heteroatom, particularly R³² and R³³ together with the nitrogen atom linking them define a morpholinyl radical. For example, the amide (D) is N-acetylmorpholine or N-formylmorpholine.

According to another preferred embodiment (D4PE), in the general formula (Ill) of (D) R³² and R³³ together with the nitrogen atom linking them define a 5-membered saturated or unsaturated heterocyclic radical which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and more preferably, R³² and R³³ together with the nitrogen atom linking them define a 5-membered saturated heterocyclic radical which optionally comprises one further nitrogen heteroatoms, most preferably R³² and R³³ together with the nitrogen atom linking them define a 5-membered saturated heterocyclic radical which comprises one further nitrogen heteroatom which is covalently bound to the carbon atom of the carbonyl group of R³¹CO, particularly R³² and R³³ together with the nitrogen atom linking them define a imidazolidinonyl radical. For example, the amide (D) is 1,3-Dimethyl-2-imidazolidinone (also referred to as dimethylethylenurea).

According to another preferred embodiment (D5PE), in the general formula (III) of (D) R³² is an acyloxy substituted alkyl group, more preferably, R³¹CO is an acyl radical having 1 to 4 carbon atoms, and R³² is an acyloxy substituted alkyl group, most preferably, R³¹CO is an acyl radical having 1 to 4 carbon atoms, R³² is an acyloxy substituted alkyl group and R³³ is C₁ to C₄ alkyl.

For example, the amide (D) is N-[2-(acetyloxy)ethyl]-N-methyl acetamide.

The composition (Q1), (Q2), or (Q3) can further optionally comprise

(E) an alcohol comprising at least two hydroxy groups which are not dissociable in the aqueous medium. The alcohol (E) is different from the components (A), (B), (C) and (D).

“Not dissociable” means that the pK_(a) value (logarithmic measure of the acid dissociation constant) for the reaction alcohol (D)→deprotonated alcohol (D)+H⁺of the hydroxy group in the neutral aqueous phase is more than 9.9, more preferably more than 11, most preferably more than 12, particularly preferably more than 13, for example more than 14 as measured in de-ionized water at 25° C. and atmospheric pressure. For example, propane1,2-diol (alpha-propylene glycol) has a pK_(a) value of 14.9 as measured in de-ionized water at 25° C. and atmospheric pressure.

If present, the alcohol (E) is preferably used as solvent in the compositions (Q1), (Q2), or (Q3).

Preferably, the alcohol (E) is a diol, triol, tetraol, pentaol, hexaol, heptaol, octaol, nonaol, decaol, or a polyol. More preferably, (E) is a diol, triol, tetraol, pentaol, or hexaol. Most preferably, (E) is a diol. Particularly most preferably, (E) is ethanediol (ethylene glycol), propanediol (propylene glycol), or butanediol (butylene glycol). Particularly, (E) is propanediol (propylene glycol). For example, (E) is propane-1,2-diol (alpha-propylene glycol).

The alcohol (E) is preferably an alcohol having 2 to 50 carbon atoms, more preferably an alcohol having 2 to 20 carbon atoms, most preferably an alcohol having 2 to 11 carbon atoms, particularly preferably an alcohol having 2 to 7 carbon atoms, in particular an alcohol having 2 to 4 carbon atoms, for example an alcohol having 3 carbon atoms.

If present, the alcohol (E) can be contained in varying amounts in the composition (Q1), (Q2), or (Q3). If present, the amount of (E) is preferably not more than 99 wt. % (wt. % stands for “percent by weight”), more preferably not more than 93 wt. %, most preferably not more than 87 wt. %, most particularly preferably not more than 80 wt. %, particularly not more than 75 wt. %, for example not more than 70 wt. %, based on the total weight of the composition (Q1), (Q2), or (Q3). If present, the amount of (E) is at least 13 wt. %, more preferably at least 20 wt. %, most preferably at least 35 wt. %, most particularly preferably at least 45 wt. %, particularly at least 55 wt. %, for example at least 60 wt. %, based on the total weight of the composition (Q1), (Q2), or (Q3).

According to another embodiment, the amount of (E) is preferably not more than 78 wt. %, more preferably not more than 67 wt. %, most preferably not more than 61 wt. %, most particularly preferably not more than 56 wt. %, particularly not more than 53 wt. %, for example not more than 50 wt. %, based on the total weight of the composition (Q1), (Q2), or (Q3). Preferably, the amount of (E) is at least 16 wt. %, more preferably at least 21 wt. %, most preferably at least 26 wt. %, most particularly preferably at least 30 wt. %, particularly at least 37 wt. %, for example at least 40 wt. %, based on the total weight of the composition (Q1), (Q2), or (Q3).

The composition (Q1), (Q2), or (Q3) can further optionally comprise

(F) a nitrogen-containing fertilizer. The nitrogen-containing fertilizer (F) is different from the components (A), (B), (C) and (D).

The nitrogen-containing fertilizer (F) preferably comprises manure, ammonium sulfate, ammonium nitrate, ammonium chloride, cyanamide, dicyandiamide (DCD), calcium nitrate, or urea-containing fertilizer (F1), more preferably comprises urea-containing fertilizer (F1), most preferably comprises urea, for example is urea.

The urea-containing fertilizer (F1) is defined as a fertilizer comprising at least one component selected from the group consisting of urea, urea ammonium nitrate (UAN), isobutylidene diurea (IBDU), crotonylidene diurea (CDU) and urea formaldehyde (UF), urea-acetaldehyde, and urea-glyoxal condensates.

In customary commercial fertilizer quality, the urea has a purity of at least 90%, and may for example be in crystalline, granulated, compacted, prilled or ground form.

If present, the fertilizer (F) can be contained in varying amounts in the composition (Q1), (Q2), or (Q3). If present, the amount of (F) is preferably not more than 99.99 wt. % (wt. % stands for “percent by weight”), more preferably not more than 99.9 wt. %, most preferably not more than 99.5 wt. %, most particularly preferably not more than 99 wt. %, particularly not more than 98 wt. %, for example not more than 97 wt. %, based on the total weight of the composition (Q1), (Q2), or (Q3). If present, the amount of (F) is preferably at least 96 wt. %, more preferably at least 93 wt. %, most preferably at least 90 wt. %, most particularly preferably at least 82 wt. %, particularly at least 70 wt. %, for example at least 50 wt. %, based on the total weight of the composition (Q1), (Q2), or (Q3).

The properties of the composition (Q1), (Q2), or (Q3)—such as stability, storage life, or stability when applied to or coated on nitrogen-containing fertilizers (F) such as urea—may depend on the pH of the corresponding composition. In general, the composition (Q1), (Q2), or (Q3) can have any pH value. The pH value of the composition (Q1), (Q2), or (Q3) is preferably not more than 14, more preferably not more than 13, most preferably not more than 12, particularly preferably not more than 11.6, particularly most preferably not more than 11.3, particularly not more than 11, for example not more than 10.7. The pH value of the composition (Q1), (Q2), or (Q3) is preferably at least 6, more preferably at least 7, most preferably at least 7.5, particularly preferably at least 8.0, particularly most preferably at least 8.2, particularly at least 8.5, for example at least 8.7. The pH value of the composition (Q1), (Q2), or (Q3) is preferably in the range of from 6 to 14, more preferably from 7 to 13, most preferably from 7.5 to 12, particularly preferably from 8 to 11.6, particularly most preferably from 8.2 to 11.3, particularly from 8.5 to 11, for example from 8.7 to 10.7.

The composition (Q1), (Q2), or (Q3) can further optionally contain at least one pH adjusting agent (G). The pH adjusting agent (G) is different from the components (A), (B), (C) and (D). In general, the pH adjusting agent (G) is a compound which is added to the composition (Q1), (Q2), or (Q3) to have its pH value adjusted to the required value. Preferably, the composition (Q1), (Q2), or (Q3) contains at least one pH adjusting agent (G). Preferred pH adjusting agents are inorganic acids, carboxylic acids, amine bases, alkali hydroxides, ammonium hydroxides, including tetraalkylammonium hydroxides. Particularly, the pH adjusting agent (G) is nitric acid, sulfuric acid, ammonia, sodium hydroxide, or potassium hydroxide. For example, the pH adjusting agent (G) is potassium hydroxide.

If present, the pH adjusting agent (G) can be contained in varying amounts in the composition (Q1), (Q2), or (Q3). If present, the amount of (G) is preferably not more than 10 wt. %, more preferably not more than 2 wt. %, most preferably not more than 0.5 wt. %, particularly not more than 0.1 wt. %, for example not more than 0.05 wt. %, based on the total weight of the corresponding composition (Q1), (Q2), or (Q3). If present, the amount of (G) is preferably at least 0.0005 wt. %, more preferably at least 0.005 wt. %, most preferably at least 0.025 wt. %, particularly at least 0.1 wt. %, for example at least 0.4 wt. %, based on the total weight of the corresponding composition (Q1), (Q2), or (Q3).

The composition (Q1), (Q2), or (Q3) can further optionally contain the compound (K) selected from the group consisting of

(K1) an amine selected from the group consisting of methyldiethanolamine, tetrahydroxypropylethylenediamine, trimethylaminoethylethanolamine, N,N,N′,N′-tetramethyl-1,6-hexanediamine, N,N′,N″-tris(dimethylaminopropyl)hexahydrotriazine, and 2,2′-dimorpholinyldiethyl ether,

(K2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups R⁴¹, wherein all groups R⁴¹ within said amine are identical, and

(K3) an amine containing not more than one amino group and at least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups R⁴², wherein at least one of the groups R⁴² bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein all groups R⁴² with said amine are identical.

(K2) or (K3) are preferably triethanolamine, tripropanolamine, diisopropanolamine, triisopropanolamine, diethanolamine, methyldiethanolamine, or methyldipropanolamine.

If present, the compound (K) can generally be contained in varying amounts in the composition (Q1), (Q2), or (Q3). If present, the amount of (K) is preferably not more than 40 wt. % (wt. % stands for “percent by weight”), more preferably not more than 30 wt. %, most preferably not more than 25 wt. %, most particularly preferably not more than 20 wt. %, particularly not more than 18 wt. %, for example not more than 15 wt. %, based on the total weight of the composition (Q1), (Q2), or (Q3).). If present, the amount of (K) is preferably at least 1 wt. %, more preferably at least 3 wt. %, most preferably at least 5 wt. %, most particularly preferably at least 8 wt. %, particularly at least 11 wt. %, for example at least 14 wt. %, based on the total weight of the composition (Q1), (Q2), or (Q3).

The composition (Q1), (Q2), or (Q3) can further optionally contain components (H) which are selected from the group consisting of auxiliaries, solvents, solid carriers, surfactants, adjuvants, thickeners, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers, binders, preservatives, antioxidants, and odorants. The component (H) is different from the components (A), (B), (C) and (D).

Suitable auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers and binders.

Suitable solvents and liquid carriers are water and organic solvents, such as mineral oil fractions of medium to high boiling point, e.g. kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e. g. toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, e.g. ethanol, propanol, butanol, cyclohexanol; glycols; DMSO; ketones, e.g. cyclohexanone; esters, e.g. lactates, carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, e.g. N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.

Suitable solid carriers or fillers are mineral earths, e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides, e.g. cellulose, starch; fertilizers, e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, e.g. cereal meal, tree bark meal, wood meal, nutshell meal, and mixtures thereof.

Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifier, dispersant, solubilizer, wetter, penetration enhancer, protective colloid, or adjuvant. Examples of surfactants are listed in McCutcheon's, Vol. 1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).

Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates. Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol ethoxylates.

Suitable nonionic surfactants are alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents. Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar-based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or alkylpolyglucosides. Examples of polymeric surfactants are home- or copolymers of vinylpyrrolidone, vinylalcohols, or vinylacetate.

Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines. Suitable amphoteric surfactants are alkylbetains and imidazolines. Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or polyethyleneamines.

Suitable adjuvants are compounds, which have a neglectable or even no pesticidal activity themselves, and which improve the biological performance of the compound I on the target. Examples are surfactants, mineral or vegetable oils, and other auxilaries. Further examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.

Suitable thickeners are polysaccharides (e.g. xanthan gum, carboxymethylcellulose), anorganic clays (organically modified or unmodified), polycarboxylates, and silicates.

Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.

Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin.

Suitable anti-foaming agents are silicones, long chain alcohols, and salts of fatty acids.

Suitable colorants (e.g. in red, blue, or green) are pigments of low water solubility and water-soluble dyes. Examples are

-   -   inorganic colorants, such as iron oxide, titan oxide, iron         hexacyanoferrate,     -   metal-complex dyes such as chromium-complex dyes, for example         Orasol Yellow 141,     -   organic colorants such as alizarin-, azo- and phthalocyanine         colorants.

Preferred colorants are metal-complex dyes, more preferably chromium-complex dyes, for example Orasol Yellow 141.

Suitable tackifiers or binders are polyvinylpyrrolidones, polyvinylacetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.

Suitable preservatives include e.g. sodium benzoate, benzoic acid, sorbic acid, and derivatives thereof.

Suitable antioxidants include sulfites, ascorbic acid, tocopherol, tocopherol acetate, tocotrienol, melatonin, carotene, beta-carotene, ubiquinol, and derivatives thereof. Tocophercol acetate is preferred as antioxidant.

Suitable odorants include perfume materials which are for example mentioned in U.S. Pat. No. 7,182,537, including allo-ocimene, Allyl cyclohexanepropionate, Allyl heptanoate, trans-Anethole, Benzyl butyrate, Camphene, Cadinene, Carvacrol, cis-3-Hexenyl tiglate, Citronellol, Citronellyl acetate, Citronellyl nitrile, Citronellyl propionate, Cyclohexylethyl acetate, Decyl Aldehyde (Capraldehyde), Dihydromyrcenol, Dihydromyrcenyl acetate, 3,7-Dimethyl-1-octanol, Diphenyloxide, Fenchyl Acetate (1,3,3-Trimethyl-2-norbornanyl acetate), Geranyl acetate, Geranyl formate, Geranyl nitrile, cis-3-Hexenyl isobutyrate, Hexyl Neopentanoate, Hexyl tiglate, alpha-Ionone, Ethyl Vanillin L80, Isoeugenol, Methyl cinnamate, Methyl dihydrojasmonate, Methyl beta-naphthyl ketone, Phenoxy ethyl isobutyrate, Vanillin L28, Isobornyl acetate, Isobutyl benzoate, Isononyl acetate, Isononyl alcohol (3,5,5-Trimethyl-1-hexanol), Isopulegyl acetate, Lauraldehyde, d-Limonene, Linalyl acetate, (-)-L-Menthyl acetate, Methyl Chavicol (Estragole), Methyl n-nonyl acetaldehyde, methyl octyl acetaldehyde, beta-Myrcene, Neryl acetate, Nonyl acetate, Non-aldehyde, p-Cymene, alpha-Pinene, beta-Pinene, alpha-Terpinene, gamma-Terpinene, alpha-Terpinyl acetate, Tetrahydrolinalool, Tetrahydromyrcenol, 2-Undecenal, Verdox (o-t-Butylcyclohexyl acetate), Vertenex (4-tert,Butylcyclohexyl acetate). Citronellyl nitrile is preferred as odorant.

According to one embodiment, individual components of the compositions (Q1), (Q2), or (Q3) such as parts of a kit or parts of a binary or ternary mixture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate.

If present, the component (H) can be contained in varying amounts in the composition (Q1), (Q2), or (Q3). If present, the amount of (H) is preferably not more than 10 wt. %, more preferably not more than 4 wt. %, most preferably not more than 2 wt. %, particularly not more than 1 wt. %, for example not more than 0.5 wt. %, based on the total weight of the corresponding composition (Q1), (Q2), or (Q3). If present, the amount of (H) is preferably at least 0.0005 wt. %, more preferably at least 0.005 wt. %, most preferably at least 0.025 wt. %, particularly at least 0.1 wt. %, for example at least 0.4 wt. %, based on the total weight of the corresponding composition (Q1), (Q2), or (Q3).

With respect to the composition (Q1), (Q2), or (Q3), the weight ratio of the mixture (A) to the aromatic alcohol (B)—in case of (Q2) or (Q3) only as far as (B) is present—is preferably between 50:1 and 1:50, more preferably between 10:1 and 1:10, most preferably between 5:1 and 1:5, particularly preferably between 3:1 and 1:3, particularly most preferably between 2:1 and 1:2, particularly between 1:1 and 1:2, for example between 1:1.5 to 1:1.8.

With respect to the composition (Q1), (Q2), or (Q3), the weight ratio of the mixture (A) to the amine (C)—in case of (Q1) or (Q3) only as far as (C) is present—is preferably between 100:1 and 1:20, more preferably between 40:1 and 1:8, most preferably between 30:1 and 1:6, particularly preferably between 20:1 and 1:5, particularly most preferably between 10:1 and 1:2, particularly between 5:1 and 1:1.2, for example between 2:1 to 1:1.

With respect to the composition (Q1), (Q2), or (Q3), the weight ratio of the mixture (A) to the amide (D)—in case of (Q1) or (Q2) only as far as (D) is present—is preferably between 50:1 and 1:50, more preferably between 10:1 and 1:10, most preferably between 5:1 and 1:5, particularly preferably between 3:1 and 1:3, particularly most preferably between 2.5:1 and 1:2, particularly between 2:1 and 1:1, for example between 1.8:1 to 1.2:1.

According to the invention, a process for treating the soil comprising applying the compositions (Q1), (Q2), or (Q3) into the soil in-furrow and/or as side-dress and/or as broadcast was found.

Preferably, said process comprises: applying the compositions (Q1), (Q2), or (Q3) by spraying it onto the soil. More preferably, said process are conducted in a way wherein the compositions (Q1), (Q2), or (Q3) are—either at the same time (i.e. simultaneously) or with a time difference (i.e. separately)—applied together with at least one nitrogen-containing fertilizer (F) into the soil in-furrow and/or as side-dress and/or as broadcast.

According to the invention, the compositions (Q1), (Q2), or (Q3) can be used as additive or as coating material for nitrogen-containing fertilizers (F), particularly for urea-containing fertilizer (F1), for example for urea. According to one preferred embodiment, the compositions (Q1), (Q2), or (Q3) are used as coating material for nitrogen-containing fertilizers (F), particularly for urea-containing fertilizer (F1), for example for urea. The nitrogen-containing fertilizer (F) cam be in crystalline, granulated, compacted, prilled or ground form, and is preferably in granulated from.

The compositions (Q1), (Q2), or (Q3) can be applied to or on nitrogen-containing fertilizers (F) by either mixing the (Q1), (Q2), or (Q3), in either liquid or solid form, with the nitrogen-containing fertilizer (F), or incorporating them into (F) by granulation, compacting or prilling, by addition to a corresponding fertilizer mixture or to a mash or melt. Preferably, the compositions (Q1), (Q2), or (Q3) are applied to the surface of existing granules, compacts or prills of the nitrogen-containing fertilizer (F)—particularly of the urea-containing fertilizer (F1)—by means of spraying, powder application or impregnating, for example. This can also be done using further auxiliaries such as adhesive promoters or encasing materials. Examples of apparatuses suitable for performing such application include plates, drums, mixers or fluidized-bed apparatus, although application may also take place on conveyor belts or their discharge points or by means of pneumatic conveyors for solids. A concluding treatment with anticaking agents and/or antidust agents is like-wise possible. The compositions (Q1), (Q2), or (Q3) are used in the context of fertilization with nitrogen-containing fertilizer (F), particularly with urea-containing fertilizer (F1). Application takes place preferably to an agriculturally or horticulturally exploited plot.

In parallel with the improvement of the utilization of nitrogen in the urea-containing, mineral and organic fertilizers, the use of the compositions (Q1), (Q2), or (Q3) has the effect that there is an Increase—in some cases considerably—in the yields or production of biomass of crop plants.

The compositions (Q1), (Q2), or (Q3) may be added to organic fertilizers, such as liquid manure, for example, during the actual storage of such fertilizers, in order thus to prevent nitrogen nutrient losses, by virtue of decelerated conversion of the individual forms of nitrogen into gaseous nitrogen compounds, which are therefore volatile, and in order as a result, at the same time, to contribute to a lowering of the ammonia load in animal stables.

In this context it is immaterial whether the compositions (Q1), (Q2), (Q3) are incorporated, by melting, for example, into the nitrogen-containing fertilizer (F), or else are applied to the fertilizer surface or applied separately from the spreading of the fertilizer, in the form, for example, of a (suspension) concentrate, a solution or a formulation.

For the below examples and the below tables, the following abbreviations have been used:

%=percent by weight (wt. %)

ad100=the percent by weight of this component is 100% minus the sum of the weight percentages (in percent by weight) of all other components comprised in the composition

BDA=Butyldiethanolamine

BZ=benzyl alcohol

(C)i=amine component (C)

(C)ii=additional amine component (C)

Coat.=coated on urea (all the data in the rows below the “coated row” are experimental data after the composition has been coated on urea)

colo.=colorant Orasol Yellow 141

conc.=concentration (e.g. amount) of NxPT in percent by weight based on the total weight of the urea fertilizer on which the composition was coated

Comp.=comparative example

DEI=Bis(hydroxyethyl)-isopropanolamine (DEIPA)

dev.=deviation, as an indicator for the stability after coated on urea, calculated as difference between the NxPT content in the heat stability test and the content in the cold stability test—both after coated on urea—, indicated as percent

DMI=1,3-Dimethyl-2-imidazolidinone (Dimethylethylenurea)

DML=Dimethyllactamide

E15=ethoxylated (5) cocoalkylamine

E25=ethoxylated (15) cocoalkylamine

Ex #=Example no.

F.ex.=formulation example

HBI=1-((2-hydroxyethyl)amino)propan-2-ol (Hydroxyethyl-bis-isopropanolamin)

Inv.=Example of the invention

LES=2-propylheptylamine ethoxylate (10 EO)

LFG=polyethyleneimine with a weight average molecular weight of 800 g/mol as measured by GPC (dry substance, at pH 4.5)

LGA=polyethyleneimine with a weight average molecular weight of 1300 g/mol as measured by GPC (dry substance, at pH 4.5)

LL=technical mixture (with a 85.20% concentration of NxPT) containing 23.8% NPPT and 76.2% NBPT

LPN=N,N′,N″-tris(dimethylaminopropyl)hexahydrotriazine

LT=technical mixture (with a 84.27% concentration of NxPT based on the total amount of the technical mixture) containing 23.7% NPPT and 76.3% NBPT, based on the total amount of NxPT within the technical mixture

HCM=Mixture of N,N-Dimethyloctanamide (50-65%) and N,N-Dimethyldecanamide (37 -50%)

MDA=Methyldiethanolamine

MPA=n-Acetyl-morpholine

MPF=n-Formyl-morpholine

NB/c=Content (percent by weight) of NBPT in cold stability test (2 weeks at 5° C.)

NP/c=Content (percent by weight) of NPPT in cold stability test (2 weeks at 5° C.)

Nx/c=Content (Percent by weight) of NxPT in cold stability test (2 weeks at 5° C.)

NB/h=Content (Percent by weight) of NBPT in heat stability test (2 weeks at 54° C.)

NP/h=Content (Percent by weight) of NPPT in heat stability test (2 weeks at 54° C.)

Nx/h=Content (Percent by weight) of NxPT in heat stability test (2 weeks at 54° C.)

NB/a=Content (Percent by weight) of NBPT in cold stability test (2 weeks at 5° C.) after coated on urea

NP/a=Content (Percent by weight) of NPPT in cold stability test (2 weeks at 5° C.) after coated on urea

Nx/a=Content (Percent by weight) of NxPT in cold stability test (2 weeks at 5° C.) after coated on urea

NB/b=Percent by weight of NBPT in heat stability test (4 weeks at 40° C. and 50% air humidity) after coated on urea

NP/b=Percent by weight of NPPT in heat stability test (4 weeks at 40° C. and 50% air humidity) after coated on urea

Nx/b=Percent by weight of NxPT in heat stability test (4 weeks at 40° C. and 50% air humidity) after coated on urea

NxPT=Mixture (A) comprising NBPT and NPPT (the content of NxPT is the sum of the content of NBPT and NPPT)

NyPT=Mixture (A) comprising NBPT and/or NPPT

NMM=N-methyl-morpholine

NMP=N-methyl-pyrrolidinone

PEI=polyethyleneimine

PG=propylene glycol

pH=pH value measured at 2% concentration

SEA=is N-[2-(acetyloxy)ethyl]-N-methyl acetamide

stabi.=storage stability of NxPT, calculated as difference between the NxPT content in the heat stability test and the content in the cold stability test, indicated as percent

TEA=triethanolamine

TPA=tocopherol acetate

visc.=viscosity in mPas

The following compositions as listed in Table 1 are preferred embodiments of the present invention.

For the preferred embodiments PE1 to PE161, the following abbreviations are used in addition to the abbreviations listed above:

(C1) is a polymeric polyamine;

(C2) is an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups R²¹, wherein at least one of the groups R²¹ is different to the other groups R²¹;

(C3) is an amine containing not more than one amino group and at least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups R²², wherein at least one of the groups R²² bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R²² is different to the other group(s) R²²;

(C4) is an amine containing at least one saturated or unsaturated C₈ to C₄₀ alkyl group R²³, and

(C5) is a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group.

(D1) is an amide according to the general formula (III)

R³¹CO—NR³²R³³

-   -   wherein     -   R³¹CO is a hydroxysubstituted acyl radical having 1 to 22 carbon         atoms;     -   R³² is H or C₁ to C₄ alkyl, and     -   R³³ is H or C₁ to C₄ alkyl.

(D2) is an amide according to the general formula (III)

R³¹CO—NR³²R³³

-   -   wherein     -   R³¹CO is a is an acyl radical having 1 to 22 carbon atoms which         do not contain a hydroxyl group;     -   R³² is H or C₁ to C₄ alkyl, and     -   R³³ is H or C₁ to C₄ alkyl.

(D3) is an amide according to the general formula (III)

R³¹CO—NR³²R³³

-   -   wherein     -   R³¹CO is an acyl radical having 1 to 22 carbon atoms;         -   R³² and R³³ together with the nitrogen atom linking them             define a 6-membered saturated heterocyclic radical which             comprises one further oxygen heteroatom.

(D4) is an amide according to the general formula (III)

R³¹CO—NR³²R³³

-   -   wherein     -   R³¹CO is an acyl radical having 1 to 22 carbon atoms;     -   R³² and R³³ together with the nitrogen atom linking them define         a 5-membered saturated heterocyclic radical which comprises one         further nitrogen heteroatom.

(D5) is an amide according to the general formula (III

R³¹CO—NR³²R³³

-   -   wherein     -   R³¹CO is an acyl radical having 1 to 22 carbon atoms;     -   R³² is an acyloxy substituted alkyl group, and     -   R³³ is H or alkyl.

TABLE 1 PE# (A) (B) (C)i (C)ii (D) (E) (K) (H) 1 NyPT ≥10% BZ 2 NyPT DMI 3 NyPT (D4) 4 NyPT HCM 5 NyPT (D2) 6 NyPT SEA 7 NyPT (D5) 8 NyPT DML 9 NyPT (D1) 10 NyPT MPA 11 NyPT MPF 12 NyPT (D3) 13 NyPT LES 14 NyPT (C4) 15 NyPT PEI 16 NyPT (C1) 17 NyPT NMM 18 NyPT (C5) 19 NyPT LES SEA 20 NyPT (C4) (D5) 21 NyPT PEI SEA 22 NyPT (C1) (D5) 23 NyPT SEA TEA 24 NyPT (D5) (K2) 25 NyPT NMM SEA 26 NyPT (C5) (D5) 27 NyPT LES DML 28 NyPT (C4) (D1) 29 NyPT PEI DML 30 NyPT (C1) (D1) 31 NyPT DML TEA 32 NyPT (D1) (K2) 33 NyPT LES PEI DML 34 NyPT (C4) (C1) (D1) 35 NyPT LES NMM DML 36 NyPT (C4) (C5) (D1) 37 NyPT LES HCM 38 NyPT (C4) (D2) 39 NyPT PEI HCM 40 NyPT (C1) (D2) 41 NyPT HCM TEA 42 NyPT (D2) (K2) 43 NyPT NMM HCM 44 NyPT (C5) (D2) 45 NyPT NMM DML 46 NyPT (C5) (D1) 47 NyPT LES DML TEA 48 NyPT (C4) (D1) (K2) 49 NyPT LES DML BDA 50 NyPT (C4) (D1) (K3) 51 NyPT LES DML MDA 52 NyPT (C4) (D1) (K3) 53 NyPT PEI LES 54 NyPT (C1) (C4) 55 NyPT LES PEI HCM 56 NyPT (C4) (C1) (D2) 57 NyPT ≥10% BZ PG 58 NyPT DMI PG 59 NyPT (D4) PG 60 NyPT HCM PG 61 NyPT (D2) PG 62 NyPT SEA PG 63 NyPT (D5) PG 64 NyPT DML PG 65 NyPT (D1) PG 66 NyPT MPA PG 67 NyPT MPF PG 68 NyPT (D3) PG 69 NyPT LES PG 70 NyPT (C4) PG 71 NyPT PEI PG 72 NyPT (C1) PG 73 NyPT NMM PG 74 NyPT (C5) PG 75 NyPT LES SEA PG 76 NyPT (C4) (D5) PG 77 NyPT PEI SEA PG 78 NyPT (C1) (D5) PG 79 NyPT SEA PG TEA 80 NyPT (D5) PG (K2) 81 NyPT NMM SEA PG 82 NyPT (C5) (D5) PG 83 NyPT LES DML PG 84 NyPT (C4) (D1) PG 85 NyPT PEI DML PG 86 NyPT (C1) (D1) PG 87 NyPT DML PG TEA 88 NyPT (D1) PG (K2) 89 NyPT LES PEI DML PG 90 NyPT (C4) (C1) (D1) PG 91 NyPT LES NMM DML PG 92 NyPT (C4) (C5) (D1) PG 93 NyPT LES HCM PG 94 NyPT (C4) (D2) PG 95 NyPT PEI HCM PG 96 NyPT (C1) (D2) PG 97 NyPT HCM PG TEA 98 NyPT (D2) PG (K2) 99 NyPT NMM HCM PG 100 NyPT (C5) (D2) PG 101 NyPT NMM DML PG 102 NyPT (C5) (D1) PG 103 NyPT LES DML PG TEA 104 NyPT (C4) (D1) PG (K2) 105 NyPT LES DML PG BDA 106 NyPT (C4) (D1) PG (K3) 107 NyPT LES DML PG MDA 108 NyPT (C4) (D1) PG (K3) 109 NyPT PEI LES PG 110 NyPT (C1) (C4) PG 111 NyPT LES PEI HCM PG 112 NyPT (C4) (C1) (D2) PG 113 NyPT ≥10% BZ LPN 114 NyPT ≥10% BZ (K1) 115 NyPT ≥10% BZ DMI 116 NyPT ≥10% BZ (D4) 117 NyPT ≥10% BZ HCM 118 NyPT ≥10% BZ (D2) 119 NyPT ≥10% BZ SEA 120 NyPT ≥10% BZ (D5) 121 NyPT ≥10% BZ DML 122 NyPT ≥10% BZ (D1) 123 NyPT ≥10% BZ MPA 124 NyPT ≥10% BZ MPF 125 NyPT ≥10% BZ (D3) 126 127 NyPT ≥10% BZ LES 128 NyPT ≥10% BZ (C4) 129 NyPT ≥10% BZ PEI 130 NyPT ≥10% BZ (C1) 131 NyPT ≥10% BZ NMM 132 NyPT ≥10% BZ (C5) 133 NyPT ≥10% BZ LES (D5) 135 NyPT ≥10% BZ PEI SEA 136 NyPT ≥10% BZ (C1) (D5) 137 NyPT ≥10% BZ SEA TEA 138 NyPT ≥10% BZ (D5) (K2) 139 NyPT ≥10% BZ NMM SEA 140 NyPT ≥10% BZ (C5) (D5) 141 NyPT ≥10% BZ LES DML 142 NyPT ≥10% BZ (C4) (D1) 143 NyPT ≥10% BZ PEI DML 144 NyPT ≥10% BZ (C1) (D1) 145 NyPT ≥10% BZ DML TEA 146 NyPT ≥10% BZ (D1) (K2) 147 NyPT ≥10% BZ LES PEI DML 148 NyPT ≥10% BZ (C4) (C1) (D1) 149 NyPT ≥10% BZ LES NMM DML 150 NyPT ≥10% BZ (C4) (C5) (D1) 151 NyPT ≥10% BZ LES HCM 152 NyPT ≥10% BZ (C4) (D2) 153 NyPT ≥10% BZ PEI HCM 154 NyPT ≥10% BZ (C1) (D2) 155 NyPT ≥10% BZ HCM TEA 156 NyPT ≥10% BZ (D2) (K2) 157 NyPT ≥10% BZ NMM HCM 158 NyPT ≥10% BZ (C5) (D2) 159 NyPT ≥10% BZ NMM DML 160 NyPT ≥10% BZ (C5) (D1) 161 NyPT ≥10% BZ LES DML TEA 162 NyPT ≥10% BZ (C4) (D1) (K2) 163 NyPT ≥10% BZ LES DML BDA 164 NyPT ≥10% BZ (C4) (D1) (K3) 165 NyPT ≥10% BZ LES DML MDA 166 NyPT ≥10% BZ (C4) (D1) (K3) 167 NyPT ≥10% BZ PEI LES 168 NyPT ≥10% BZ (C1) (C4) 169 NyPT ≥10% BZ LES PEI HCM 147 NyPT ≥10% BZ (C4) (C1) (D2) 148 NyPT ≥10% BZ DEI 149 NyPT ≥10% BZ HBI 150 NyPT ≥10% BZ (C2) 151 NyPT ≥10% BZ E15 152 NyPT ≥10% BZ E25 153 NyPT ≥10% BZ (C4) 154 NyPT ≥10% BZ (C3) 155 NyPT DEI PG 156 NyPT HBI PG 157 NyPT (C2) PG 158 NyPT E15 PG 159 NyPT E25 PG 160 NyPT (C4) PG 161 NyPT (C3) PG

The advantages of the invention are that the enhancement of the stability of the (thio)phosphoric acid triamide(s)—particularly when applied to or coated on nitrogen-containing fertilizers such as urea—and a relatively long storage life—particularly before being applied to or coated on nitrogen-containing fertilizers—was achieved with the compositions (Q1), (Q2), (Q3). Moreover, the compositions (Q1), (Q2), (Q3) do not adversely affect the urease-inhibiting effect and/or activity of the (thio)phosphoric acid triamide. Last, but not least, the compositions (Q1), (Q2), (Q3) can be easily and safely packaged, transported and shipped, even in large quantities, and can be easily and safely handled and applied for soil treatment, even in large quantities

The examples which follow illustrate the invention without restricting it.

PREPARATION OF THE FORMULATIONS Preparation of the Formulation

According to the ratios and components as specified in Table 2, all components were mixed, and the resulting mixture was stirred until complete dissolution of the solid and analyzed for the content of NBPT, NPPT, NxPT (by HPLC), viscosity, dissolution (2%) in water and pH. For example, in case of Ex. #310092, the technical mixture LT (25% pure NxPT) was mixed with 50.08% benzyl alcohole and 10% LFG, 10% DML and 0.25% colo. The mixture was stirred until complete dissolution of the solid and analyzed for NxPT content (by HPLC), viscosity, dissolution (2%) in water and pH.

Formulation Storage Stability

The mixture of each example (e.g. Ex. #310092) was stored in closed bottles for 14 days at 54° C. (referred to as heat stability test in the following) and then analyzed for the content of NxPT. The mixture of each example (e.g. Ex. #310092) was also stored in closed bottles for 14 days at 5° C. (referred to as cold stability test in the following) and then analyzed for the content of NxPT. The storage stability in % was calculated as difference between the content in the heat stability test and the content in the cold stability test.

Coating of Urea Example 1.1

500 g granulated urea was charged to a rotating drum (Type Hege 11) and 2 g of the formulation of each example (e.g. Ex. #310092) was sprayed on the urea using a rotating disc. The homogeneous coated urea was discharged after 1 min and analyzed for the content of NBPT, NPPT, NxPT (by HPLC).

Stability on Urea

The coated urea sample of 300 g was stored in a petri dish for 4 weeks at 50% humidity in a climate chamber. For analysis the sample was homogenized and analyzed for the content of NBPT, NPPT, NxPT (by HPLC)

The content of NxPT measured by HPLC measurement is always the sum of the both components NBPT and NBPT.

Viscosity was measured at the undiluted formulation with a cone-plate rheometer AR 2000ex (TA Instruments) at shear rate of 100s⁻¹ and 20° C.

The pH value was measured at 2% concentration in CIPAC water D.

All examples of the inventions are liquid, clear compositions which are either colourless or yellow.

TABLE 2 Examples of the compositions of the invention and of comparative compositions, and data on their viscosity, pH value, storage stability and stability after coated on urea Inv. Inv. Inv. Inv. Inv. Inv. Inv. Inv. part 1 of 11 Ex# 310007 310008 310010 310011 310012 310013 310014 310015 (A) 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT PG ad100 ad100 ad100 ad100 ad100 ad100 ad100 ad100 BZ   20% (C)i 20% LES (C)ii (D) 20% DMI 20% HCM 20% SEA 20% DML 20% MPA 20% MPF other colo. visc. 39 37 47 50 49 51 44 100 pH 8.2 8.1 8.4 7.5 8.1 8.2 8.2 9.6 NB/c 18.95% 19.20% 19.08% 18.81% 18.89% 19.05% 18.68% 19.01% NP/c  5.82%  5.92%  5.85%  5.84%  5.75%  5.83%  5.72%  5.82% Nx/c 24.77% 25.12% 24.93% 24.65% 24.64% 24.88% 24.40% 24.83% NB/h 18.32% 18.86% 18.63% 18.57% 18.65% 18.68% 18.08% 18.51% NP/h  5.77%  5.92%  5.85%  5.91%  5.81%  5.84%  5.63%  5.77% Nx/h 24.09% 24.78% 24.48% 24.48% 24.46% 24.52% 23.71% 24.28% stabi. 97.25% 98.67% 98.20% 99.29% 99.27% 98.58% 97.14% 97.80% Coat. conc. NB/a NP/a Nx/a NB/b NP/b Nx/b dev. part 2 of 11 Ex# 310016 310017 310021 310024 310025 310026 310027 310028 (A) 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT PG ad100 ad100 ad100 ad100 ad100 ad100 ad100 ad100 BZ (C)i 20% LFG 20% LGA 20% NMM 10% LES 10% LFG 10% LGA 10% TEA 10% NMM (C)ii (D) 10% SEA 10% SEA 10% SEA 10% SEA 10% SEA other colo. visc. 423 598 39 46 167 173 71 46 pH 10.7 10.6 9.4 9.3 10.3 10.2 9.2 9.1 NB/c 18.99% 19.06% 18.93% 18.85% 18.72% 18.71% 18.84% 18.73% NP/c  5.83%  5.86%  5.79%  5.97%  5.90%  5.92%  6.13%  6.04% Nx/c 24.82% 24.92% 24.72% 24.82% 24.62% 24.63% 24.97% 24.77% NB/h 18.50% 18.25% 18.80% 18.58% 18.59% 18.80% 18.27% 18.73% NP/h  5.78%  5.70%  6.06%  5.89%  5.87%  5.94%  5.92%  5.96% Nx/h 24.28% 23.95% 24.86% 24.47% 24.46% 24.74% 24.19% 24.69% stabi. 97.81% 96.10% 100.54%  98.59% 99.36% 100.45%  96.88% 99.70% Coat. conc. NB/a NP/a Nx/a NB/b NP/b Nx/b dev. part 3 of 11 Ex# 310029 310031 310032 310034 310035 310036 310037 310039 (A) 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT PG ad100 ad100 ad100 ad100 ad100 ad100 ad100 ad100 BZ (C)i 10% LES 10% LGA 10% TEA 10% LES 10% LES 10% LES 10% LES 10% LGA (C)ii 10% LFG 10% LGA 10% NMM (D) 10% DML 10% DML 10% DML 10% DML 10% DML 10% DML 10% HCM 10% HCM other colo. visc. 67 161 71 179 211 55 60 167 pH 9.4 10.4 9.3 10.5 10.4 9.4 9.4 10.4 NB/c 18.79% 19.06% 19.03% 18.51% 18.71% 18.98% 18.96% 18.84% NP/c  5.80%  5.90%  5.88%  5.73%  5.76%  6.08%  5.88%  5.83% Nx/c 24.59% 24.96% 24.91% 24.24% 24.47% 25.06% 24.84% 24.67% NB/h 18.87% 18.98% 18.71% 18.62% 18.74% 18.98% 18.93% 18.79% NP/h  5.83%  5.86%  5.80%  5.76%  5.79%  6.03%  5.87%  5.82% Nx/h 24.70% 24.84% 24.51% 24.38% 24.53% 25.01% 24.80% 24.61% stabi. 100.46%  99.52% 98.37% 100.60%  100.22%  99.80% 99.83% 99.73% Coat. conc. NB/a NP/a Nx/a NB/b NP/b Nx/b dev. part 4 of 11 Ex# 310040 310041 310044 310045 310046 310047 310048 310049 (A) 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT PG ad100 ad100 ad100 ad100 ad100 ad100 ad100 ad100 BZ (C)i 10% TEA 10% NMM 1% LFG 3% LFG 10% LFG (C)ii (D) 10% HCM 10% HCM 20% HCM 20% SEA 20% DML 20% DML 20% DML 20% DML other colo.  0.25%  0.25%  0.25%  0.25%  0.25%  0.25% visc. 72 46 53 53 51 58 71 144 pH 9.4 9.3 8.8 7.9 8.5 9.6 10.1 10.5 NB/c 18.83% 18.64% 18.48% 18.77% 18.70% 18.61% 18.62% 18.62% NP/c  5.78%  6.10%  5.79%  5.90%  5.80%  5.81%  5.81%  5.78% Nx/c 24.61% 24.74% 24.27% 24.67% 24.50% 24.42% 24.43% 24.40% NB/h 18.54% 18.78% 18.50% 18.46% 18.67% 18.75% 18.67% 18.67% NP/h  5.75%  5.95%  5.79%  5.82%  5.78%  5.83%  5.82%  5.80% Nx/h 24.29% 24.73% 24.29% 24.28% 24.45% 24.58% 24.49% 24.47% stabi. 98.70% 100.00%  100.08%  98.43% 99.80% 100.65%  100.26%  100.30%  Coat. conc.  0.10%  0.09%  0.10%  0.10%  0.10%  0.10% NB/a 0.057% 0.060% 0.064% 0.063% 0.065% 0.067% NP/a 0.017% 0.019% 0.020% 0.019% 0.020% 0.021% Nx/a 0.074% 0.079% 0.084% 0.082% 0.085% 0.088% NB/b 0.004% 0.008% 0.010% 0.011% 0.024% 0.054% NP/b 0.002% 0.003% 0.004% 0.004% 0.008% 0.017% Nx/b 0.006% 0.011% 0.014% 0.015% 0.032% 0.071% dev. −91.89%   −86.08%   −83.33%   −81.71%   −62.35%   −19.32%   part 5 of 11 Ex# 310050 310051 310052 310053 310059 310060 310061 310062 (A) 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT PG ad100 ad100 ad100 ad100 50.33% 55.33% 50.33% 50.33% BZ (C)i 1% NMM 3% NMM 10% NMM 20% NMM 10% LES 5% LES 5% NMM 5% TEA (C)ii 5% LES 5% LES (D) 20% DML 20% DML 20% DML 20% DML 10% DML 10% DML 10% DML 10% DML other colo.  0.25%  0.25%  0.25%  0.25%  0.25%  0.25%  0.25%  0.25% visc. 55 51 48 43 73 66 62 76 pH 8.7 8.9 9.2 9.3 9.4 9.2 9.3 9.4 NB/c 19.13% 18.87% 18.59% 20.40% 19.00% 19.10% 19.05% 18.95% NP/c  5.93%  5.88%  5.86%  6.42%  6.01%  6.04%  6.04%  5.93% Nx/c 25.06% 24.75% 24.45% 26.82% 25.01% 25.14% 25.09% 24.88% NB/h 19.05% 19.00% 19.26% 21.64% 19.17% 19.10% 19.30% 18.94% NP/h  5.92%  5.88%  5.93%  6.90%  6.02%  5.99%  6.04%  5.93% Nx/h 24.97% 24.88% 25.19% 28.54% 25.19% 25.09% 25.34% 24.87% stabi. 99.64% 100.53%  103.05%  106.40%  100.74%  99.81% 101.02%  99.98% Coat. conc.  0.10%  0.10%  0.09%  0.10%  0.10%  0.09%  0.10%  0.10% NB/a 0.067% 0.062% 0.061% 0.048% 0.068% 0.065% 0.065% 0.066% NP/a 0.021% 0.019% 0.019% 0.015% 0.021% 0.020% 0.020% 0.020% Nx/a 0.088% 0.081% 0.080% 0.063% 0.089% 0.085% 0.085% 0.086% NB/b 0.011% 0.009% 0.009% 0.010% 0.012% 0.011% 0.008% 0.037% NP/b 0.004% 0.003% 0.003% 0.003% 0.002% 0.002% 0.001% 0.007% Nx/b 0.015% 0.012% 0.012% 0.013% 0.014% 0.013% 0.009% 0.044% dev. −82.95%   −85.19%   −85.00%   −79.37%   −84.27%   −84.71%   −89.41%   −48.84%   part 6 of 11 Ex# 310063 310064 310065 310066 310077 310078 310079 310080 (A) 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT PG 50.33% 50.33% 53.33% 48.33% 60.08% 55.08% 50.08% 60.08% BZ (C)i 5% LES 5% LES 2% LFG 2% LFG 10% LFG 15% LFG 20% LFG 8% LFG (C)ii 5% LES 5% LES 2% LES (D) 10% DML 10% DML 10% DML 10% DML other 5% BDA 5% MDA colo.  0.25%  0.25%  0.25%  0.25%  0.25%  0.25%  0.25%  0.25% visc. 69 71 83 72 175 286 486 153 pH 9.8 9.7 10.0 9.9 10.5 10.6 10.7 10.4 NB/c 18.86% 18.78% 18.84% 18.97% 19.12% 19.18% 19.15% 19.15% N P/c  5.96%  5.93%  5.96%  6.03%  6.17%  6.19%  6.19%  6.22% Nx/c 24.82% 24.71% 24.80% 25.00% 25.29% 25.37% 25.34% 25.37% NB/h 18.83% 18.93% 18.79% 19.16% 19.02% 19.13% 18.99% 18.98% N P/h  5.92%  5.96%  5.91%  6.01%  6.07%  6.07%  6.06%  5.98% Nx/h 24.75% 24.89% 24.70% 25.17% 25.09% 25.20% 25.05% 24.96% stabi. 99.70% 100.72%  99.61% 100.66%  99.24% 99.33% 98.84% 98.38% Coat. conc.  0.10%  0.10%  0.10%  0.10%  0.08%  0.08%  0.08%  0.08% Target Target Target Target N B/a 0.063% 0.068% 0.068% 0.067% 0.056% 0.058% 0.058% 0.054% NP/a 0.019% 0.021% 0.021% 0.021% 0.018% 0.019% 0.019% 0.018% Nx/a 0.082% 0.089% 0.089% 0.088% 0.074% 0.077% 0.077% 0.072% NB/b 0.038% 0.040% 0.017% 0.017% 0.048% 0.053% 0.048% 0.041% NP/b 0.008% 0.008% 0.003% 0.003% 0.014% 0.016% 0.014% 0.011% Nx/b 0.046% 0.048% 0.020% 0.020% 0.062% 0.069% 0.062% 0.052% dev. −43.90%   −46.07%   −77.53%   −77.27%   −16.22%   −10.39%   −19.48%   −27.78%   part 7 of 11 Ex# 310081 310082 310083 310084 310086 310087 310073 310088 (A) 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT PG 50.08% 50.08% 50.08% 50.08% 49.08% 47.08% BZ 70.33% 60.08% (C)i 10% LFG 10% LFG 8% LFG 8% LFG 8% LFG 8% LFG 10% LFG (C)ii 2% LES 2% LES 2% LES 2% LES (D) 10% DML 10% HCM 10% DML 10% HCM 10% DML 10% DML other 1% TPA 3% TPA colo.  0.25%  0.25%  0.25%  0.25%  0.25%  0.25%  0.25% visc. 152 156 127 127 129 140 11 34 pH 10.5 10.5 10.4 10.4 10.4 10.4 8.5 10.6 NB/c 19.11% 19.23% 19.45% 19.66% 19.22% 18.91% 19.21% 19.17% NP/c  6.16%  6.23%  6.24%  6.33%  6.16%  6.07%  6.23%  6.19% Nx/c 25.27% 25.46% 25.69% 25.99% 25.38% 24.98% 25.44% 25.36% NB/h 19.03% 19.11% 19.34% 19.26% 19.48% 19.57% 18.28% 19.00% NP/h  5.96%  6.01%  6.08%  6.06%  6.10%  5.97%  5.93%  6.13% Nx/h 24.99% 25.12% 25.42% 25.32% 25.58% 25.54% 24.21% 25.13% stabi. 98.90% 98.66% 98.94% 97.44% 100.78%  102.24%   −4.85%    −0.91%   Coat. conc.  0.08%  0.08%  0.08%  0.08%  0.08%  0.08%  0.08% Target Target Target Target Target Target Target NB/a 0.057% 0.055% 0.057% 0.053% 0.056% 0.057% 0.060% NP/a 0.019% 0.018% 0.018% 0.017% 0.018% 0.019% 0.019% Nx/a 0.076% 0.073% 0.075% 0.070% 0.074% 0.076% 0.079% NB/b 0.040% 0.044% 0.042% 0.045% 0.040% 0.038% 0.049% NP/b 0.011% 0.012% 0.011% 0.013% 0.011% 0.010% 0.014% Nx/b 0.051% 0.056% 0.053% 0.058% 0.051% 0.048% 0.063% dev.  −32.9%    −23.3%    −29.3%    −17.1%    −31.1%    −36.8%   −20.25%   part 8 of 11 Ex# 310089 310090 310091 310092 310093 310094 310095 310096 (A) 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT 29.67% LT PG BZ 55.08% 50.08% 60.08% 50.08% 50.08% 50.08% 50.08% 55.08% (C)i 15% LFG 20% LFG 8% LFG 10% LFG 10% LFG 8% LFG 8% LFG (C)ii 2% LES 2% LES 2% LES (D) 10% DML 10% HCM 10% DML 10% HCM other 15% LPN colo.  0.25%  0.25%  0.25%  0.25%  0.25%  0.25%  0.25%  0.25% visc. 70 121 32 42 40 34 34 35 pH 10.6 10.7 10.5 10.5 10.5 10.4 10.5 11.4 NB/c 19.33% 19.08% 19.25% 19.11% 19.00% 19.12% 19.68% 17.77% NP/c  6.23%  6.15%  6.20%  6.17%  6.16%  6.14%  6.33%  5.73% Nx/c 25.56% 25.23% 25.45% 25.28% 25.16% 25.26% 26.01% 23.50% NB/h 18.95% 19.07% 19.02% 18.97% 18.86% 19.08% 19.34% 15.60% N P/h  6.15%  6.18%  6.14%  6.07%  6.08%  6.14%  6.24%  4.92% Nx/h 25.10% 25.25% 25.16% 25.04% 24.94% 25.22% 25.58% 20.52% stabi.  −1.82%    0.09%  −1.15%    −0.97%    −0.89%    −0.15%    −1.65%   −12.68%   Coat. conc.  0.08%  0.08%  0.08%  0.08%  0.08%  0.08%  0.08%  0.08% Target Target Target Target Target Target Target Target NB/a 0.061% 0.058% 0.061% 0.057% 0.059% 0.062% 0.065% 0.059% NP/a 0.019% 0.018% 0.019% 0.018% 0.018% 0.019% 0.020% 0.019% Nx/a 0.080% 0.076% 0.080% 0.075% 0.077% 0.081% 0.085% 0.078% NB/b 0.052% 0.051% 0.046% 0.049% 0.050% 0.051% 0.048% 0.050% NP/b 0.016% 0.016% 0.013% 0.014% 0.015% 0.015% 0.014% 0.015% Nx/b 0.068% 0.067% 0.059% 0.063% 0.065% 0.066% 0.062% 0.065% dev. −15.00%   −11.84%   −26.25%   −16.00%   −15.58%   −18.52%   −27.06%   −16.67%   part 9 of 11 Ex# 310104 310105 310106 310108 310109 310110 310111 (A) 29.67% LT 29.67% LT 25% NBPT 29.34% LL 29.34% LL 29.34% LL 29.34% LL PG BZ 50.08% 40.08% 54.75% 50.41% 40.41% 60.41% 60.41% (C)i 20% LFG 30% LFG 20% LFG 20% LFG 30% LFG 10% DEI 10% HBI (C)ii (D) other colo.  0.25%  0.25%  0.25%  0.25%  0.25%  0.25%  0.25% visc. 132 345 94 115 314 18 18 pH 10.5 10.6 10.7 12.3 9.1 8.7 9.1 NB/c 18.56% 18.62% 25.17% 19.79% 19.72% 19.32% 19.78% NP/c  5.82%  5.89%  0.00%  6.19%  6.19%  6.06%  6.12% Nx/c 24.38% 24.51% 25.17% 25.98% 25.91% 25.38% 25.90% NB/h 18.70% 19.01% 25.59% 19.90% 19.90% 19.41% 19.40% NP/h  5.95%  5.94%  0.00%  6.21%  6.18%  6.16%  5.88% Nx/h 24.65% 24.95% 25.59% 26.11% 26.08% 25.57% 25.28% stabi.  1.11%  1.80%  1.67%  0.50%  0.66%  0.75%  −2.39%   Coat. conc.  0.08%  0.08%  0.08%  0.08%  0.08%  0.08%  0.08% Target Target Target Target Target Target Target NB/a 0.058% 0.057% 0.077% 0.060% 0.059% 0.063% 0.065% NP/a 0.019% 0.019% 0.000% 0.019% 0.019% 0.019% 0.020% Nx/a 0.077% 0.076% 0.077% 0.079% 0.078% 0.082% 0.085% NB/b NP/b Nx/b dev. part 10 of 11 Ex# 310112 310113 310114 310115 310116 310117 310118 310119 (A) 29.34% LL 29.34% LL 29.34% LL 29.34% LL 29.34% LL 29.34% LL 29.34% LL 29.34% LL PG 60.41% 60.41% BZ 60.41% 60.41% 40.41% 40.41% 50.41% 50.41% (C)i 10% E15 10% E25 30% E15 30% E25 20% DEI 10% HBI 10% DEI 10% HBI (C)ii (D) other colo. 0.25% 0.25% 0.25% 0.25% 0.25% 0.25% 0.25% 0.25% visc. 17 20 42 63 30 31 78 80 pH 8.9 9.3 9.1 9.1 9.0 9.1 8.9 9.1 NB/c 19.66% 19.85% 19.65% 19.73% 19.69% 19.83% 19.67% 19.83% NP/c  6.16%  6.20%  6.16%  6.20%  6.98%  6.04%  6.09%  6.14% Nx/c 25.82% 26.05% 25.81% 25.93% 26.67% 25.87% 25.76% 25.97% NB/h 19.50% 19.65% 19.55% 19.68% 19.53% 19.61% 19.32% 19.76% NP/h  6.40%  6.39%  6.00%  6.11%  6.70%  5.94%  6.05%  6.20% Nx/h 25.90% 26.04% 25.55% 25.79% 26.23% 25.55% 25.37% 25.96% stabi.  0.31%  −0.04%    −1.01%    −0.54%    −1.65%    −1.24%    −1.51%    −0.04%   Coat. conc.  0.08%  0.08%  0.08%  0.08%  0.08%  0.08%  0.08%  0.08% Target Target Target Target Target Target Target Target NB/a 0.064% 0.062% 0.060% 0.059% 0.059% 0.058% 0.056% 0.064% NP/a 0.020% 0.019% 0.019% 0.018% 0.018% 0.018% 0.017% 0.020% Nx/a 0.084% 0.081% 0.079% 0.077% 0.077% 0.076% 0.073% 0.084% NB/b NP/b Nx/b dev. NMP (at least in amounts as applied in Ex# 310043) is toxicologically objectionable. part 11 of 11 Ex# 310120 310121 310122 310123 310022 310043 310085 (A) 29.34% LL 29.34% LL 29.34% LL 29.34% LL 29.67% LT 29.67% LT 29.67% LT PG 60.41% 60.41% 40.41% 40.41% ad100 ad100 55.08% BZ (C)i 10% E15 10% E25 30% E15 30% E25 (C)ii (D) other 20% LPN 20% NMP 15% LPN colo.  0.25%  0.25%  0.25%  0.25%  0.25%  0.25% visc. 75 81 114 140 181 36 141 pH 9.1 9.3 9.3 9.3 11.2 8.5 11.3 NB/c 20.05% 19.70% 20.04% 19.70% 18.39% 18.68% 18.12% NP/c  6.25%  6.14%  6.25%  6.13%  5.71%  5.86%  5.83% Nx/c 26.30% 25.84% 26.29% 25.83% 24.10% 24.54% 23.95% NB/h 20.07% 19.77% 19.82% 19.39% 15.67% 18.52% 16.38% NP/h  6.28%  6.18%  6.18%  6.09%  4.91%  5.81%  5.21% Nx/h 26.35% 25.95% 26.00% 25.48% 20.58% 24.33% 21.59% stabi.  0.19%  0.43%  −1.10%    −1.36%   85.41% 99.16% 90.11% Coat. conc.  0.08%  0.08%  0.08%  0.08%  0.10%  0.08% Target Target Target Target Target NB/a 0.063% 0.062% 0.062% 0.062% 0.064% 0.053% NP/a 0.020% 0.019% 0.019% 0.019% 0.019% 0.016% Nx/a 0.083% 0.081% 0.081% 0.081% 0.083% 0.069% NB/b 0.005% 0.039% NP/b 0.002% 0.010% Nx/b 0.007% 0.049% dev. −91.57%   −29.0%  

Further specific embodiments of the invention are described in the following:

1. An composition comprising:

-   -   (A) a mixture comprising at least one (thio)phosphoric acid         triamide according to the general formula (I)

R¹R²N—P(X)(NH₂)₂,

-   -   wherein     -   X is oxygen or sulfur;     -   R¹ is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl,         or dialkylaminocarbonyl group;     -   R² is H, or     -   R¹ and R² together with the nitrogen atom linking them define a         5- or 6-membered saturated or unsaturated heterocyclic radical,         which optionally comprises 1 or 2 further heteroatoms selected         from the group consisting of nitrogen, oxygen, and sulfur,     -   and     -   (B) an aromatic alcohol according to the general formula (II)

R¹¹—C(R¹²)(R¹³)—OH ,

-   -   in an amount of more than 10 wt. % based on the total weight of         the composition,     -   wherein     -   R11 is aryl or alkylaryl;     -   R¹² is H or alkyl;     -   R¹³ is H or alkyl.

2. The composition according to embodiment 1, wherein in the general formula (I) of (A) X is sulfur.

3. The composition according to embodiment 1 or 2, wherein in the general formula (I) of (A) R¹ is C₁-C₂₀ alkyl and R² is H.

4. The composition according to anyone of the embodiments 1 to 3, wherein the mixture (A) comprises N-n-butylthiophosphoric acid triamide (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT).

5. The composition according to embodiment 1, wherein the mixture (A) comprises at least two different (thio)phosphoric acid triamides having structures of the general formula (I) and wherein said at least two different (thio)phosphoric acid triamides differ in at least one of radicals R¹ or R².

6. The composition according to embodiment 5, wherein one of said at least two different (thio)phosphoric acid triamides is N-n-butylthiophosphoric acid triamide.

7. The composition according to anyone of the embodiments 1 to 6, wherein in the general formula (II) of (B) R¹² and R¹³ is H.

8. The composition according to anyone of the embodiments 1 to 7, wherein in the general formula (II) of (B) R¹¹ is aryl.

9. The composition according to anyone of the embodiments 1 to 8, wherein in the general formula (II) of (B) R¹¹ is phenyl.

10. The composition according to anyone of the embodiments 1 to 9, wherein (B) is benzyl alcohol.

11. The composition according to embodiment 1, wherein

-   -   the mixture (A) comprises N-n-butylthiophosphoric acid triamide         (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT) and     -   (B) is benzyl alcohol.

12. The composition according to anyone of the embodiments 1 to 11, further comprising (C) at least one amine selected from the group consisting of

-   -   (C1) a polymeric polyamine, and     -   (C2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups R²¹, wherein at least one of the groups R²¹ is different         to the other groups R²¹, and     -   (C3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups         R²², wherein at least one of the groups R²² bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein at least one of the groups R²² is different to the other         group(s) R²², and     -   (C4) an amine containing at least one saturated or unsaturated         C₈ to C₄₀ alkyl group R²³, and     -   (C5) a saturated or unsaturated heterocyclic amine which         contains at least one oxygen atom as ring atom and which does         not contain a further alkoxy group.

13. The composition according to anyone of the embodiments 1 to 12, further comprising (C) an amine which is

-   -   (C1) a polymeric polyamine.

14. The composition according to anyone of the embodiments 1 to 12, wherein (C1) is a polyalkylene imine.

15. The composition according to anyone of the embodiments 1 to 12, wherein (C1) is a polyethylene imine.

16. The composition according to anyone of the embodiments 1 to 12, further comprising (C) an amine which is

-   -   (C2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups, wherein at least one of the groups R²¹ is different to         the other groups R²¹.

17. The composition according to anyone of the embodiments 1 to 12, further comprising (C2) an amine containing not more than one amino group and at least three hydroxy-substituted C₂ to C₃ alkyl groups which are covalently bound to the amino group.

18. The composition according to anyone of the embodiments 1 to 12, further comprising (C2) an amine selected from the group consisting of Bis(hydroxyethyl)-isopropanolamine (DEIPA), and 1,1′-((2-Hydroxyethyl)imino)dipropan-2-ol.

19. The composition according to anyone of the embodiments 1 to 12, further comprising (C) an amine which is

-   -   (C3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups,         wherein at least one of said alkyl groups bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein at least one of the groups R²² is different to the other         group(s) R²².

20. The composition according to anyone of the embodiments 1 to 12, further comprising (C3) an amine selected from the group consisting of 1-((2-hydroxyethyl)amino)propan-2-ol, and N-Methyl-N-hydroxyethyl-isopropanolamine.

21. The composition according to anyone of the embodiments 1 to 12, further comprising (C) an amine which is

-   -   (C4) an amine containing at least one saturated or unsaturated         C₈ to C₄₀ alkyl group R²³.

22. The composition according to anyone of the embodiments 1 to 12, further comprising (C4) an amine containing at least one saturated or unsaturated C₈ to C₁₉ alkyl group R²³.

23. The composition according to anyone of the embodiments 1 to 12, further comprising (C4) an amine selected from the group consisting of ethoxylated (2) cocoalkylamine, ethoxylated (5) cocoalkylamine, ethoxylated (15) cocoalkylamine, ethoxylated (2) oleylamine, lauryl-dimethylamine, oleyl-dimethylamine, and 2-propylheptylamine ethoxylate (5 EO), 2-propylheptylamine ethoxylate (10 EO), and 2-propylheptylamine ethoxylate (20 EO).

24. The composition according to anyone of the embodiments 1 to 12, further comprising (C) an amine which is

-   -   (C5) a saturated or unsaturated heterocyclic amine which contain         at least one oxygen atom as ring atom and which do not contain a         further alkoxy group.

25. The composition according to anyone of the embodiments 1 to 12, further comprising (C5) an amine which is N-methyl morpholine.

26. The composition according to anyone of the embodiments 1 to 25, further comprising (D) at least one amide according to the general formula (III)

R³¹CO—NR³²R³³

-   -   wherein     -   R³¹CO is an acyl radical having 1 to 22 carbon atoms;     -   R³² is H or alkyl, and     -   R³³ is H or alkyl, or     -   R³² and R³³ together with the nitrogen atom linking them define         a 5- or 6-membered saturated or unsaturated heterocyclic         radical, which optionally comprises 1 or 2 further heteroatoms         selected from the group consisting of nitrogen, oxygen, and         sulfur.

27. The composition according to anyone of the embodiments 1 to 26, wherein in the general formula (III) of (D) R³² is H or C₁ to C₄ alkyl, and R³³ is H or C₁ to C₄ alkyl.

28. The composition according to anyone of the embodiments 1 to 27, wherein in the general formula (III) of (D) R³¹CO is a hydroxysubstituted acyl radical having 1 to 22 carbon atoms.

29. The composition according to anyone of the embodiments 1 to 28, wherein (D) is a N,N-dialkyl amide based on lactic acid, citric acid, tartaric acid, ricinoleic acid, 12-hydroxy stearic acid, or their mixtures.

30. The composition according to anyone of the embodiments 1 to 29, wherein (D) is a lactic acid N,N-dimethylamide.

31. The composition according to anyone of the embodiments 1 to 27, wherein in the general formula (III) of (D) R³¹CO does not contain a hydroxy group.

32. The composition according to anyone of the embodiments 1 to 27 and 31, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 6 to 12 carbon atoms.

33. The composition according to anyone of the embodiments 1 to 27 and 31 to 32, wherein (D) is selected from the group consisting of N,N-dimethyloctanamide, N,N-dimethylnonanamide, and N,N-dimethyldecanamide.

34. The composition according to anyone of the embodiments 1 to 27 and 31, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 1 to 3 carbon atoms.

35. The composition according to anyone of the embodiments 1 to 26, wherein in the general formula (III) of (D) R³² and R³³ together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur.

36. The composition according to anyone of the embodiments 1 to 26 and 35, wherein in the general formula (III) of (D) R³² and R³³ together with the nitrogen atom linking them define a 6-membered saturated heterocyclic radical which comprises one further oxygen heteroatom.

37. The composition according to anyone of the embodiments 1 to 26 and 35 to 36, wherein (D) is N-acetylmorpholine or N-formylmorpholine.

38. The composition according to anyone of the embodiments 1 to 26 and 35, wherein in the general formula (III) of (D) R³² and R³³ together with the nitrogen atom linking them define a 5-membered saturated heterocyclic radical which comprises one further nitrogen heteroatom.

39. The composition according to anyone of the embodiments 1 to 26, 35, and 38, wherein (D) is 1,3-dimethyl-2-imidazolidinone.

40. The composition according to anyone of the embodiments 1 to 27, wherein in the general formula (III) of (D) R³² is an acyloxy substituted alkyl group.

41. The composition according to anyone of the embodiments 1 to 27, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 1 to 4 carbon atoms, R³² is an acyloxy substituted alkyl group and R³³ is C₁ to C₄ alkyl.

42. The composition according to anyone of the embodiments 1 to 27, wherein (D) is N-[2-(acetyloxy)ethyl]-N-methyl acetamide.

43. The composition according to anyone of the embodiments 1 to 42, further comprising (E) an alcohol comprising at least two hydroxy groups which are not dissociable in the aqueous medium.

44. The composition according to anyone of the embodiments 1 to 42, further comprising (E) propane-1,2-diol (alpha-propylene glycol).

45. The composition according to anyone of the embodiments 1 to 44, further comprising a compound (K) selected from the group consisting of

-   -   (K1) an amine selected from the group consisting of         methyldiethanolamine, tetrahydroxypropylethylenediamine,         trimethylaminoethylethanolamine,         N,N,N1,N1-tetramethyl-1,6-hexanediamine,         N,N′,N″-tris(dimethylaminopropyl)hexahydrotriazine, and         2,2′-dimorpholinyldiethyl ether,     -   (K2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups R⁴¹, wherein all groups R⁴¹ within said amine are         identical, and     -   (K3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups         R⁴², wherein at least one of the groups R⁴² bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein all groups R⁴² with said amine are identical.

46. The composition according to anyone of the embodiments 1 to 45, further comprising (F) a nitrogen-containing fertilizer.

47. The composition according to anyone of the embodiments 1 to 45, further comprising (F1) a urea-containing fertilizer comprising at least one component selected from the group consisting of urea, urea ammonium nitrate (UAN), isobutylidene diurea (IBDU), crotonylidene diurea (CDU) and urea formaldehyde (UF), urea-acetaldehyde, and urea-glyoxal condensates.

48. The composition according to anyone of the embodiments 1 to 45, further comprising (F) a nitrogen-containing fertilizer which comprises urea.

49. Process for treating the soil comprising:

-   -   applying the composition according to anyone of the embodiments         1 to 48 into the soil infurrow and/or as side-dress and/or as         broadcast.

50. Process according to embodiment 49 comprising:

-   -   applying the composition by spraying it onto the soil.

51. Process according to embodiment 49, wherein the composition is—either at the same time or with a time difference—applied together with at least one nitrogen-containing fertilizer (F) into the soil in-furrow and/or as side-dress and/or as broadcast.

52. Use of the composition according to anyone of the embodiments 1 to 45 as additive or coating material for nitrogen-containing fertilizers (F).

101. An composition comprising:

(A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I)

R¹R²N—P(X)(NH₂)₂,

-   -   wherein     -   X is oxygen or sulfur;     -   R¹ is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl,         or dialkylaminocarbonyl group;     -   R² is H, or     -   R¹ and R² together with the nitrogen atom linking them define a         5- or 6-membered saturated or unsaturated heterocyclic radical,         which optionally comprises 1 or 2 further heteroatoms selected         from the group consisting of nitrogen, oxygen, and sulfur,     -   and

(C) at least one amine selected from the group consisting of

-   -   (C1) a polymeric polyamine, and     -   (C2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups R²¹, wherein at least one of the groups R²¹ is different         to the other groups R²¹, and     -   (C3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups         R²², wherein at least one of the groups R²² bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein at least one of the groups R²² is different to the other         group(s) R²², and     -   (C4) an amine containing at least one saturated or unsaturated         C₈ to C₄₀ alkyl group R²³, and     -   (C5) a saturated or unsaturated heterocyclic amine which         contains at least one oxygen atom as ring atom and which does         not contain a further alkoxy group.

102. The composition according to embodiment 101, wherein in the general formula (I) of (A) X is sulfur.

103. The composition according to embodiment 101 or 102, wherein in the general formula (I) of (A) R¹ is C₁-C₂₀ alkyl and R² is H.

104. The composition according to anyone of the embodiments 101 to 103, wherein the mixture (A) comprises N-n-butylthiophosphoric acid triamide (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT).

105. The composition according to embodiment 101, wherein the mixture (A) comprises at least two different (thio)phosphoric acid triamides having structures of the general formula (I) and wherein said at least two different (thio)phosphoric acid triamides differ in at least one of radicals R¹ or R².

106. The composition according to embodiment 105, wherein one of said at least two different (thio)phosphoric acid triamides is N-n-butylthiophosphoric acid triamide.

107. The composition according to anyone of the embodiments 101 to 106, wherein (C) is

-   -   (C1) a polymeric polyamine.

108. The composition according to anyone of the embodiments 101 to 106, wherein (C) is (C1) which is a polyalkylene imine.

109. The composition according to anyone of the embodiments 101 to 106, wherein (C) is (C1) which is a polyethylene imine.

110. The composition according to anyone of the embodiments 101 to 106, wherein (C) is

-   -   (C2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups R²¹, wherein at least one of the groups R²¹ is different         to the other groups R²¹.

111. The composition according to anyone of the embodiments 101 to 106, wherein (C) is (C2) an amine containing not more than one amino group and at least three hydroxy-substituted C₂ to C₃ alkyl groups which are covalently bound to the amino group.

112. The composition according to anyone of the embodiments 101 to 106, wherein (C) is (C2) an amine selected from the group consisting of Bis(hydroxyethyl)-isopropanolamine (DEIPA), and 1,1′-((2-Hydroxyethyl)imino)dipropan-2-ol.

113. The composition according to anyone of the embodiments 101 to 106, wherein (C) is

-   -   (C3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups         R²², wherein at least one of said alkyl groups bears the alkoxy         or hydroxy substituent at a secondary or tertiary carbon atom         and wherein at least one of the groups R²² is different to the         other group(s) R22_(.)

114. The composition according to anyone of the embodiments 101 to 106, wherein (C) is (C3) an amine selected from the group consisting of 1-((2-hydroxyethyl)amino)propan-2-ol, and N-Methyl-N-hydroxyethyl-isopropanolamine.

115. The composition according to anyone of the embodiments 101 to 106, wherein (C) is (C) an amine which is

-   -   (C4) an amine containing at least one saturated or unsaturated         C₈ to C₄₀ alkyl group R²³.

116. The composition according to anyone of the embodiments 101 to 106, wherein (C) is (C4) an amine containing at least one saturated or unsaturated C₈ to C₁₉ alkyl group R²³.

117. The composition according to anyone of the embodiments 101 to 106, wherein (C) is (C4) an amine selected from the group consisting of ethoxylated (2) cocoalkylamine, ethoxylated (5) cocoalkylamine, ethoxylated (15) cocoalkylamine, ethoxylated (2) oleylamine, lauryl-dimethylamine, oleyl-dimethylamine, and 2-propylheptylamine ethoxylate (5 EO), 2-propylheptylamine ethoxylate (10 EO), and 2-propylheptylamine ethoxylate (20 EO).

118. The composition according to anyone of the embodiments 101 to 106, wherein (C) is

-   -   (C5) a saturated or unsaturated heterocyclic amine which contain         at least one oxygen atom as ring atom and which do not contain a         further alkoxy group.

119. The composition according to anyone of the embodiments 101 to 106, wherein (C) is (C5) an amine which is N-methyl morpholine.

120. The composition according to embodiment 101, wherein

-   -   the mixture (A) comprises N-n-butylthiophosphoric acid triamide         (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT) and     -   (C) is (C1) a polymeric polyamine which is polyethyleneimine.

121. The composition according to anyone of the embodiments 101 to 120, further comprising

-   -   (B) an aromatic alcohol according to the general formula (II)

R¹¹—C(R¹²)(R¹³)—OH,

-   -   wherein     -   R¹¹ is aryl or alkylaryl;     -   R¹² is H or alkyl;     -   R¹³ is H or alkyl.

122. The composition according to anyone of the embodiments 101 to 121, further comprising (B), wherein in the general formula (II) of (B) R¹² and R¹³ is H.

123. The composition according to anyone of the embodiments 101 to 122, further comprising (B), wherein in the general formula (II) of (B) R¹¹ is aryl.

124. The composition according to anyone of the embodiments 101 to 123, further comprising (B), wherein in the general formula (II) of (B) R¹¹ is phenyl.

125. The composition according to anyone of the embodiments 101 to 124, further comprising (B), wherein (B) is benzyl alcohol.

126. The composition according to anyone of the embodiments 101 to 125, further comprising

-   -   (D) at least one amide according to the general formula (III)

R³¹CO—NR³²R³³

-   -   wherein     -   R³¹CO is an acyl radical having 1 to 22 carbon atoms;     -   R³² is H or alkyl, and     -   R³³ is H or alkyl, or     -   R³² and R³³ together with the nitrogen atom linking them define         a 5- or 6-membered saturated or unsaturated heterocyclic         radical, which optionally comprises 1 or 2 further heteroatoms         selected from the group consisting of nitrogen, oxygen, and         sulfur.

127. The composition according to anyone of the embodiments 101 to 126, wherein in the general formula (III) of (D) R³² is H or C₁ to C₄ alkyl, and R³³ is H or C₁ to C₄ alkyl.

128. The composition according to anyone of the embodiments 101 to 127, wherein in the general formula (III) of (D) R³¹CO is a hydroxysubstituted acyl radical having 1 to 22 carbon atoms.

129. The composition according to anyone of the embodiments 101 to 128, wherein (D) is a N,N-dialkyl amide based on lactic acid, citric acid, tartaric acid, ricinoleic acid, 12-hydroxy stearic acid, or their mixtures.

130. The composition according to anyone of the embodiments 101 to 129, wherein (D) is a lactic acid N,N-dimethylamide.

131. The composition according to anyone of the embodiments 101 to 127, wherein in the general formula (III) of (D) R³¹CO does not contain a hydroxy group.

132. The composition according to anyone of the embodiments 101 to 127 and 131, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 6 to 12 carbon atoms.

133. The composition according to anyone of the embodiments 101 to 127 and 131 to 132, wherein (D) is selected from the group consisting of N,N-dimethyloctanamide, N,N-dimethylnonanamide, and N,N-dimethyldecanamide.

134. The composition according to anyone of the embodiments 101 to 127 and 131, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 1 to 3 carbon atoms.

135. The composition according to anyone of the embodiments 101 to 126, wherein in the general formula (III) of (D) R³² and R³³ together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur.

136. The composition according to anyone of the embodiments 101 to 126 and 135, wherein in the general formula (III) of (D) R³² and R³³ together with the nitrogen atom linking them define a 6-membered saturated heterocyclic radical which comprises one further oxygen heteroatom.

137. The composition according to anyone of the embodiments 101 to 126 and 135 to 136, wherein (D) is N-acetylmorpholine or N-formylmorpholine.

138. The composition according to anyone of the embodiments 101 to 126 and 135, wherein in the general formula (III) of (D) R³² and R³³ together with the nitrogen atom linking them define a 5-membered saturated heterocyclic radical which comprises one further nitrogen heteroatom.

139. The composition according to anyone of the embodiments 101 to 126, 135, and 138, wherein (D) is 1,3-dimethyl-2-imidazolidinone.

140. The composition according to anyone of the embodiments 101 to 127, wherein in the general formula (III) of (D) R³² is an acyloxy substituted alkyl group.

141. The composition according to anyone of the embodiments 101 to 127, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 1 to 4 carbon atoms, R³² is an acyloxy substituted alkyl group and R³³ is C₁ to C₄ alkyl.

142. The composition according to anyone of the embodiments 101 to 127, wherein (D) is N-[2-(acetyloxy)ethyl]-N-methyl acetamide.

143. The composition according to anyone of the embodiments 101 to 142, further comprising (E) an alcohol comprising at least two hydroxy groups which are not dissociable in the aqueous medium.

144. The composition according to anyone of the embodiments 101 to 142, further comprising (E) propane-1,2-diol (alpha-propylene glycol).

145. The composition according to anyone of the embodiments 101 to 144, further comprising a compound (K) selected from the group consisting of

-   -   (K1) an amine selected from the group consisting of         methyldiethanolamine, tetrahydroxypropylethylenediamine,         trimethylaminoethylethanolamine,         N,N,N′,N′-tetramethyl-1,6-hexanediamine,         N,N′,N″-tris(dimethylaminopropyl)hexahydrotriazine, and         2,2′-dimorpholinyldiethyl ether,     -   (K2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups R⁴¹, wherein all groups R⁴¹ within said amine are         identical, and     -   (K3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups         R⁴², wherein at least one of the groups R⁴² bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein all groups R⁴² with said amine are identical.

146. The composition according to anyone of the embodiments 101 to 145, further comprising (F) a nitrogen-containing fertilizer.

147. The composition according to anyone of the embodiments 101 to 145, further comprising (F1) a urea-containing fertilizer comprising at least one component selected from the group consisting of urea, urea ammonium nitrate (UAN), isobutylidene diurea (IBDU), crotonylidene diurea (CDU) and urea formaldehyde (UF), urea-acetaldehyde, and urea-glyoxal condensates.

148. The composition according to anyone of the embodiments 101 to 145, further comprising (F) a nitrogen-containing fertilizer which comprises urea.

149. Process for treating the soil comprising:

-   -   applying the composition according to anyone of the embodiments         101 to 148 into the soil in-furrow and/or as side-dress and/or         as broadcast.

150. Process according to embodiment 149 comprising:

-   -   applying the composition by spraying it onto the soil. 151.         Process according to embodiment 149, wherein the composition         is—either at the same time or with a time difference—applied         together with at least one nitrogen-containing fertilizer (F)         into the soil in-furrow and/or as side-dress and/or as         broadcast.

152. Use of the composition according to anyone of the embodiments 101 to 145 as additive or coating material for nitrogen-containing fertilizers (F).

201. An composition comprising:

-   -   (A) a mixture comprising at least one (thio)phosphoric acid         triamide according to the general formula (I)

R¹R²N—P(X)(NH²)²,

-   -   wherein     -   X is oxygen or sulfur;     -   R¹ is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl,         or dialkylaminocarbonyl group;     -   R² is H, or     -   R¹ and R² together with the nitrogen atom linking them define a         5- or 6-membered saturated or unsaturated heterocyclic radical,         which optionally comprises 1 or 2 further heteroatoms selected         from the group consisting of nitrogen, oxygen, and sulfur,     -   and     -   (D) at least one amide according to the general formula (III)

R³¹CO—NR³²R³³

-   -   wherein     -   R³¹CO is an acyl radical having 1 to 22 carbon atoms;     -   R³² is H or alkyl, and     -   R³³ is H or alkyl, or     -   R³² and R³³ together with the nitrogen atom linking them define         a 5- or 6-membered saturated or unsaturated heterocyclic         radical, which optionally comprises 1 or 2 further heteroatoms         selected from the group consisting of nitrogen, oxygen, and         sulfur.

202. The composition according to embodiment 201, wherein in the general formula (I) of (A) X is sulfur.

203. The composition according to embodiment 201 or 202, wherein in the general formula (I) of (A) R¹ is C₁-C₂₀ alkyl and R² is H.

204. The composition according to anyone of the embodiments 201 to 203, wherein the mixture (A) comprises N-n-butylthiophosphoric acid triamide (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT).

205. The composition according to embodiment 201, wherein the mixture (A) comprises at least two different (thio)phosphoric acid triamides having structures of the general formula (I) and wherein said at least two different (thio)phosphoric acid triamides differ in at least one of radicals R¹ or R².

206. The composition according to embodiment 205, wherein one of said at least two different (thio)phosphoric acid triamides is N-n-butylthiophosphoric acid triamide.

207. The composition according to anyone of the embodiments 201 to 206, wherein in the general formula (III) of (D) R³² is H or C₁ to C₄ alkyl, and R³³ is H or C₁ to C₄ alkyl.

208. The composition according to anyone of the embodiments 201 to 207, wherein in the general formula (III) of (D) R³¹CO is a hydroxysubstituted acyl radical having 1 to 22 carbon atoms.

209. The composition according to anyone of the embodiments 201 to 208, wherein (D) is a N,N-dialkyl amide based on lactic acid, citric acid, tartaric acid, ricinoleic acid, 12-hydroxy stearic acid, or their mixtures.

210. The composition according to anyone of the embodiments 201 to 209, wherein (D) is a lactic acid N,N-dimethylamide.

211. The composition according to anyone of the embodiments 201 to 207, wherein in the general formula (III) of (D) R³¹CO does not contain a hydroxy group.

212. The composition according to anyone of the embodiments 201 to 207 and 211, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 6 to 12 carbon atoms.

213. The composition according to anyone of the embodiments 201 to 207 and 211 to 212, wherein (D) is selected from the group consisting of N,N-dimethyloctanamide, N,N-dimethylnonanamide, and N,N-dimethyldecanamide.

214. The composition according to anyone of the embodiments 201 to 207 and 211, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 1 to 3 carbon atoms.

215. The composition according to anyone of the embodiments 201 to 206, wherein in the general formula (III) of (D) R³² and R³³ together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur.

216. The composition according to anyone of the embodiments 201 to 206 and 215, wherein in the general formula (III) of (D) R³² and R³³ together with the nitrogen atom linking them define a 6-membered saturated heterocyclic radical which comprises one further oxygen heteroatom.

217. The composition according to anyone of the embodiments 201 to 206 and 215 to 216, wherein (D) is N-acetylmorpholine or N-formylmorpholine.

218. The composition according to anyone of the embodiments 201 to 206 and 215, wherein in the general formula (III) of (D) R³² and R³³ together with the nitrogen atom linking them define a 5-membered saturated heterocyclic radical which comprises one further nitrogen heteroatom.

219. The composition according to anyone of the embodiments 201 to 206, 215, and 218, wherein (D) is 1,3-dimethyl-2-imidazolidinone.

220. The composition according to anyone of the embodiments 201 to 207, wherein in the general formula (III) of (D) R³² is an acyloxy substituted alkyl group.

221. The composition according to anyone of the embodiments 201 to 207, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 1 to 4 carbon atoms, R³² is an acyloxy substituted alkyl group and R³³ is C₁ to C₄ alkyl.

222. The composition according to anyone of the embodiments 201 to 207, wherein (D) is N-[2-(acetyloxy)ethyl]-N-methyl acetamide.

223. The composition according to embodiment 201, wherein

-   -   the mixture (A) comprises N-n-butylthiophosphoric acid triamide         (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT) and     -   (D) is an N,N-dialkyl amide based on lactic acid, citric acid,         tartaric acid, ricinoleic acid, 12-hydroxy stearic acid, or         their mixtures.

224. The composition according to anyone of the embodiments 201 to 223, further comprising (B) an aromatic alcohol according to the general formula (II)

R¹¹—C(R¹²)(R¹³)—OH,

-   -   wherein     -   R¹¹ is aryl or alkylaryl;     -   R¹² is H or alkyl;     -   R¹³ is H or alkyl.

225. The composition according to embodiment 224, wherein in the general formula (II) of (B) R¹² and R¹³ is H.

226. The composition according to anyone of the embodiments 224 to 225, wherein in the general formula (II) of (B) R¹¹ is aryl.

227. The composition according to anyone of the embodiments 224 to 226, wherein in the general formula (II) of (B) R¹¹ is phenyl.

228. The composition according to anyone of the embodiments 201 to 227, further comprising (B), wherein (B) is benzyl alcohol.

229. The composition according to anyone of the embodiments 201 to 228, further comprising (C) at least one amine selected from the group consisting of

-   -   (C1) a polymeric polyamine, and     -   (C2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups R²¹, wherein at least one of the groups R²¹ is different         to the other groups R²¹, and     -   (C3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups         R²², wherein at least one of the groups R²² bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein at least one of the groups R²² is different to the other         group(s) R²², and     -   (C4) an amine containing at least one saturated or unsaturated         C₈ to C₄₀ alkyl group R²³, and     -   (C5) a saturated or unsaturated heterocyclic amine which         contains at least one oxygen atom as ring atom and which does         not contain a further alkoxy group.

230. The composition according to anyone of the embodiments 201 to 229, further comprising (C) an amine which is

-   -   (C1) a polymeric polyamine.

231. The composition according to anyone of the embodiments 201 to 229, wherein (C1) is a polyalkylene imine.

232. The composition according to anyone of the embodiments 201 to 229, wherein (C1) is a polyethylene imine.

233. The composition according to anyone of the embodiments 201 to 229, further comprising (C) an amine which is

-   -   (C2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups, wherein at least one of the groups R²¹ is different to         the other groups R²¹.

234. The composition according to anyone of the embodiments 201 to 229, further comprising (C2) an amine containing not more than one amino group and at least three hydroxy-substituted C₂ to C₃ alkyl groups which are covalently bound to the amino group.

235. The composition according to anyone of the embodiments 201 to 229, further comprising (C2) an amine selected from the group consisting of Bis(hydroxyethyl)-isopropanolamine (DEIPA), and 1,1′-((2-Hydroxyethyl)imino)dipropan-2-ol.

236. The composition according to anyone of the embodiments 201 to 229, further comprising (C) an amine which is

-   -   (C3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups,         wherein at least one of said alkyl groups bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein at least one of the groups R²² is different to the other         group(s) R²².

237. The composition according to anyone of the embodiments 201 to 229, further comprising (C3) an amine selected from the group consisting of 1-((2-hydroxyethyl)amino)propan-2-ol, and N-Methyl-N-hydroxyethyl-isopropanolamine.

238. The composition according to anyone of the embodiments 201 to 229, further comprising (C) an amine which is

-   -   (C4) an amine containing at least one saturated or unsaturated         C₈ to C₄₀ alkyl group R²³.

239. The composition according to anyone of the embodiments 201 to 229, further comprising (C4) an amine containing at least one saturated or unsaturated C₈ to C₁₉ alkyl group R²³.

240. The composition according to anyone of the embodiments 201 to 229, further comprising (C4) an amine selected from the group consisting of ethoxylated (2) cocoalkylamine, ethoxylated (5) cocoalkylamine, ethoxylated (15) cocoalkylamine, ethoxylated (2) oleylamine, lauryl-dimethylamine, oleyl-dimethylamine, and 2-propylheptylamine ethoxylate (5 EO), 2-propylheptylamine ethoxylate (10 EO), and 2-propylheptylamine ethoxylate (20 EO).

241. The composition according to anyone of the embodiments 201 to 229, further comprising (C) an amine which is

-   -   (C5) a saturated or unsaturated heterocyclic amine which contain         at least one oxygen atom as ring atom and which do not contain a         further alkoxy group.

242. The composition according to anyone of the embodiments 201 to 229, further comprising (C5) an amine which is N-methyl morpholine.

243. The composition according to anyone of the embodiments 201 to 242, further comprising (E) an alcohol comprising at least two hydroxy groups which are not dissociable in the aqueous medium.

244. The composition according to anyone of the embodiments 201 to 242, further comprising (E) propane-1,2-diol (alpha-propylene glycol).

245. The composition according to anyone of the embodiments 201 to 244, further comprising a compound (K) selected from the group consisting of

-   -   (K1) an amine selected from the group consisting of         methyldiethanolamine, tetrahydroxypropylethylenediamine,         trimethylaminoethylethanolamine,         N,N,N′,N′-tetramethyl-1,6-hexanediamine,         N,N′,N″-tris(dimethylaminopropyl)hexahydrotriazine, and         2,2′-dimorpholinyldiethyl ether,     -   (K2) an amine containing not more than one amino group and at         least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl         groups R⁴¹, wherein all groups R⁴¹ within said amine are         identical, and     -   (K3) an amine containing not more than one amino group and at         least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups         R⁴², wherein at least one of the groups R⁴² bears the alkoxy or         hydroxy substituent at a secondary or tertiary carbon atom and         wherein all groups R⁴² with said amine are identical.

246. The composition according to anyone of the embodiments 201 to 245, further comprising (F) a nitrogen-containing fertilizer.

247. The composition according to anyone of the embodiments 201 to 245, further comprising (F1) a urea-containing fertilizer comprising at least one component selected from the group consisting of urea, urea ammonium nitrate (UAN), isobutylidene diurea (IBDU), crotonylidene diurea (CDU) and urea formaldehyde (UF), urea-acetaldehyde, and urea-glyoxal condensates. 248. The composition according to anyone of the embodiments 201 to 245, further comprising (F) a nitrogen-containing fertilizer which comprises urea.

249. Process for treating the soil comprising:

-   -   applying the composition according to anyone of the embodiments         201 to 248 into the soil in-furrow and/or as side-dress and/or         as broadcast.

250. Process according to embodiment 249 comprising:

-   -   applying the composition by spraying it onto the soil.

251. Process according to embodiment 249, wherein the composition is—either at the same time or with a time difference—applied together with at least one nitrogen-containing fertilizer (F) into the soil in-furrow and/or as side-dress and/or as broadcast.

252. Use of the composition according to anyone of the embodiments 201 to 245 as additive or coating material for nitrogen-containing fertilizers (F). 

1-34. (canceled)
 35. A composition comprising: (A) a mixture comprising at least one (thio)phosphoric acid triamide according to the general formula (I) R¹R²N—P(X)(NH₂)₂, wherein X is oxygen or sulfur; R¹ is a C₁ to C₂₀ alkyl, C₃ to C₂₀ cycloalkyl, C₆ to C₂₀ aryl, or dialkylaminocarbonyl group; R² is H, or R¹ and R² together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur, and (D) at least one amide according to the general formula (III) R³¹CO—NR³²R³³ wherein R³¹CO is an acyl radical having 1 to 22 carbon atoms; R³² is H or alkyl, and R³³ is H or alkyl, or R³² and R³³ together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical, which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur.
 36. The composition according to claim 35, wherein the mixture (A) comprises N-n-butylthiophosphoric acid triamide (NBPT) and/or N-n-propylthiophosphoric acid triamide (NPPT).
 37. The composition according to claim 35, wherein in the general formula (III) of (D) R³² is H or C₁ to C₄ alkyl, and R³³ is H or C₁ to C₄ alkyl.
 38. The composition according to claim 35, wherein in the general formula (III) of (D) R³¹CO is a hydroxysubstituted acyl radical having 1 to 22 carbon atoms.
 39. The composition according to claim 35, wherein (D) is a N,N-dialkyl amide based on lactic acid, citric acid, tartaric acid, ricinoleic acid, 12-hydroxy stearic acid, or their mixtures.
 40. The composition according to claim 35, wherein (D) is a lactic acid N,N-dimethylamide.
 41. The composition according to claim 35, wherein in the general formula (III) of (D) R³¹CO does not contain a hydroxy group.
 42. The composition according to claim 35, wherein (D) is selected from the group consisting of N,N-dimethyloctanamide, N,N-dimethylnonanamide, and N,N-dimethyldecanamide.
 43. The composition according to claim 35, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 1 to 3 carbon atoms.
 44. The composition according to claim 35, wherein in the general formula (III) of (D) R³² and R³³ together with the nitrogen atom linking them define a 5- or 6-membered saturated or unsaturated heterocyclic radical which optionally comprises 1 or 2 further heteroatoms selected from the group consisting of nitrogen, oxygen, and sulfur.
 45. The composition according to claim 35, wherein in the general formula (III) of (D) R³² is an acyloxy substituted alkyl group.
 46. The composition according to claim 35, wherein in the general formula (III) of (D) R³¹CO is an acyl radical having 1 to 4 carbon atoms, R³² is an acyloxy substituted alkyl group and R³³ is C₁ to C₄ alkyl.
 47. The composition according to claim 35, further comprising (B) an aromatic alcohol according to the general formula (II) R¹¹—C(R¹²)(R¹³)—OH, wherein is aryl or alkylaryl; R¹² is H or alkyl; R¹³ is H or alkyl.
 48. The composition according to claim 35, further comprising (C) at least one amine selected from the group consisting of (C1) a polymeric polyamine, and (C2) an amine containing not more than one amino group and at least three alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups R²¹, wherein at least one of the groups R²¹ is different to the other groups R²¹, and (C3) an amine containing not more than one amino group and at least two alkoxy- or hydroxy-substituted C₂ to C₁₂ alkyl groups R²², wherein at least one of the groups R²² bears the alkoxy or hydroxy substituent at a secondary or tertiary carbon atom and wherein at least one of the groups R²² is different to the other group(s) R²², and (C4) an amine containing at least one saturated or unsaturated C₈ to C₄₀ alkyl group R²³, and (C5) a saturated or unsaturated heterocyclic amine which contains at least one oxygen atom as ring atom and which does not contain a further alkoxy group.
 49. The composition according to claim 35, wherein (C1) is a polyethylene imine.
 50. The composition according to claim 35, further comprising (E) an alcohol comprising at least two hydroxy groups which are not dissociable in the aqueous medium.
 51. The composition according to claim 35, further comprising (E) propane-1,2-diol (alpha-propylene glycol). 